# Red Phosphorus‐Induced Transformation of Gold Mesh into Crystalline Gold Phosphide Mesh

https://mdr.nims.go.jp/datasets/e4ade9d5-e5c4-4b28-b169-e2768200fddd

## File

- [template.pdf](https://mdr.nims.go.jp/filesets/c74c6080-f8f6-4f2e-8bbc-1b65a0ef48e3/download) ([Detail](https://mdr.nims.go.jp/filesets/c74c6080-f8f6-4f2e-8bbc-1b65a0ef48e3.md))

## Id

e4ade9d5-e5c4-4b28-b169-e2768200fddd

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-12-25T06:04:40.644843Z

## Updated at

2026-04-30T03:01:11.491392Z

## Published at

2026-08-24T23:29:29.514438Z

## Doi

https://doi.org/10.48505/nims.6072

## First published url

https://doi.org/10.1002/pssr.202500298

## Date published

2025-08-25

## Recorded date published

2025-10

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Red Phosphorus‐Induced Transformation of Gold Mesh into Crystalline Gold
    Phosphide Mesh
  title_type: original
  lang: en

## Description

- description: "Among transition metal phosphides, gold phosphide (Au2P3) is particularly
    uncommon and lacks established synthesis methods for large-scale or structurally
    controlled materials, thus hindering its functional applications. This study introduces
    a synthetic strategy involving annealing gold mesh in red phosphorus vapor within
    a sealed quartz tube reactor, enabling a direct structural transformation into
    crystalline Au2P3 while preserving macroscopic geometry.\r\nComprehensive characterization
    using X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray
    spectroscopy, and X-ray photoelectron spectroscopy confirms successful formation,
    revealing covalent Au─P bonding and a semiconducting nature validated by density
    functional theory simulations, which accurately predict lattice parameters and
    electronic properties. This\r\nmethod opens possibilities for practical applications
    of Au2P3."
  description_type: abstract
  lang: und

## Creator

- name: Hajime Suzuki
  role: author
- name: Shusaku Shoji
  role: author
  orcid: https://orcid.org/0000-0002-8481-2633
  organization: National Institute for Materials Science
- name: Fernando Garcia‐Escobar
  role: author
- name: Tomoya Tashiro
  role: author
- name: Hideki Abe
  role: author
  orcid: https://orcid.org/0000-0002-8392-7586
  organization: National Institute for Materials Science
- name: Keisuke Takahashi
  role: author
  orcid: https://orcid.org/0000-0002-9328-1694
  organization: National Institute for Materials Science

## Contact agent



## Publisher

organization: Wiley

## Managing organization



## Keyword

- subject: Gold Phosphide
  schema: not_defined

## Rights

- description: 'This is the peer reviewed version of the following article: Suzuki
    Hajime, Shoji Shusaku, Garcia-Escobar Fernando, Tashiro Tomoya, Abe Hideki, Takahashi
    Keisuke, Phys. Status Solidi RRL, 2025, 19, e2500298, which has been published
    in final form at https://doi.org/10.1002/pssr.202500298. This article may be used
    for non-commercial purposes in accordance with Wiley Terms and Conditions for
    Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise
    transformed into a derivative work, without express permission from Wiley or by
    statutory rights under applicable legislation. Copyright notices must not be removed,
    obscured or modified. The article must be linked to Wiley’s version of record
    on Wiley Online Library and any embedding, framing or otherwise making available
    the article or pages thereof by third parties from platforms, services and websites
    other than Wiley Online Library must be prohibited.'
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2025-08-25
end_date: 2026-08-25

## Journal

- title: Physica Status Solidi-Rapid Research Letters
  issn: '18626254'
  volume: '19'
  issue: '10'
  article_number: '2500298'

## Conference



## Related item



## Funding

- identifier: JPMJER1903
  funder_name: Exploratory Research for Advanced Technology

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

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  content_type: application/pdf
  size: 2615670
  md5: 97a22afa949a90bd91eb0d9489fc1b8d

## Thumbnail

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