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説明:

Micro-particles with an internal helical liquid crystalline (LC) molecular order serve as efficient and highly compact circularly polarized luminescence (CPL) emitters. However, the coupling between CPL emission and the interior LC molecular order remains poorly understood at the single particle level. Here, we synthesized microspheres from a LC monomer RM23 together with a fluorescent dye and a chiral additive (R/S-BPy) and investigated their CPL properties. Polarized optical microscopy and angle-dependent CPL observations at a single-particle level revealed randomly distributed one-handed helical domains in each sphere, leading to CPL emission with an average dissymmetry factor value |glum| of 0.05 regardless the observation angle. The color of the CPL emission is tunable in the range of 450 to 700 nm by varying the fluorescent dyes doped in the spheres.

権利情報:

• Creative Commons BY Attribution 4.0 International
  

キーワード: Liquid crystal, circularly polarized luminescence, microspheres

刊行年月日: 2025-12-31

出版者: Taylor & Francis

掲載誌:

• Science and Technology of Advanced Materials (ISSN: 14686996) vol. 26 2509486

研究助成金:

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5521

公開URL: https://doi.org/10.1080/14686996.2025.2509486

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更新時刻: 2025-07-16 16:14:56 +0900

MDRでの公開時刻: 2025-06-06 08:20:09 +0900