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Metal–support interaction engineering is considered an efficient strategy for optimizing the catalytic activity. Nevertheless, the fine regulation of metal–support interactions as well as understanding the corresponding catalytic mechanisms (particularly those of non-carbon support-based counterparts) remains challenging. Herein, a controllable adsorption–impregnation strategy was proposed for the preparation of a porous nonlayered 2D NiO nanoflake support anchored with different forms of Pt nanoarchitectures, i.e. single atoms, clusters and nanoparticles. Benefiting from the unique porous architecture of NiO nanosheets, abundant active defect sites facilitated the immobilization of Pt single atoms onto the NiO crystal, resulting in NiO lattice distortion and thus changing the valence state of Pt, chemical bonding, and the coordination environment of the metal center. The synergy of the porous NiO support and the unexpected Pt single atom–NiO interactions effectively accelerated mass transfer and reduced the reaction kinetic barriers, contributing to a significantly enhanced mass activity of 5.59 A mgPt−1 at an overpotential of 0.274 V toward the electrocatalytic oxygen evolution reaction (OER) while 0.42 A mgPt−1 at a potential of 0.7 V vs. RHE for the methanol oxidation reaction (MOR) in an alkaline system, respectively. This work may offer fundamental guidance for developing metal–loaded/dispersed support nanomaterials toward electrocatalysis through the fine regulation of metal–support interactions.

権利情報:

• https://creativecommons.org/licenses/by-nc/3.0/legalcode
  

キーワード: Electrocatalysis, Water oxidation, Metanol oxidation

刊行年月日: 2024-05-27

出版者: Royal Society of Chemistry (RSC)

掲載誌:

• Chemical Science (ISSN: 20416520) vol. 15 issue. 26 p. 10172-10181

研究助成金:

• National Natural Science Foundation of China U20A20123
• National Natural Science Foundation of China 51874357

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1039/d4sc00454j

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更新時刻: 2024-09-03 08:30:13 +0900

MDRでの公開時刻: 2024-09-03 08:30:13 +0900