Journal article Shape‐Persistent Anthracene‐Based Macrocycles Prepared by Reversible Boronic Ester Formation: Crystallization and Structural Analysis
Shoma Kasahara (author) (Search by this author)
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Takayuki Okumura (author) (Search by this author)
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Mitsuaki Yamauchi (author) (Search by this author)
ORCID https://orcid.org/0000-0003-0005-5960 (unauthenticated)
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Yoshiyuki Mizuhata (author) (Search by this author)
ORCID https://orcid.org/0000-0001-5301-0024 (unauthenticated)
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Naoki Aratani (author) (Search by this author)
ORCID https://orcid.org/0000-0002-3181-6526 (unauthenticated)
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Hiroko Yamada (author) (Search by this author)
ORCID https://orcid.org/0000-0002-2138-5902 (unauthenticated)
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Citation
Shoma Kasahara, Hironobu Hayashi, Takayuki Okumura, Michio Matsumoto, Mitsuaki Yamauchi, Yoshiyuki Mizuhata, Naoki Aratani, Hiroko Yamada. Shape‐Persistent Anthracene‐Based Macrocycles Prepared by Reversible Boronic Ester Formation: Crystallization and Structural Analysis. ChemPlusChem. 2025, 90 (5), e202500014. https://doi.org/10.1002/cplu.202500014

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(abstract)

可逆的なボロン酸エステル形成により、構造が明確に決まった大環状化合物を合成した。これらの大環状化合物は、リンカーユニットを変えることで調整可能な内部空洞を有する。また、これらの大環状化合物は、溶液中でも固体基板上でも容易に結晶化することを見出した。フェニルリンカーを持つ大環状化合物は、両側の嵩高い置換基が隣接分子による空洞の充填を防ぐため、擬ナノカプセル様に振る舞うことを明らかにした。

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Keyword: Macrocycle, Single crystal, Reversible bond formation, Porous material, Anthracene

Date published: 2025-04-04

Publisher: Wiley

Journal:

  • ChemPlusChem (ISSN: 21926506) vol. 90 issue. 5 e202500014

Funding:

Manuscript type: Publisher's version (Version of record)

MDR DOI:

First published URL: https://doi.org/10.1002/cplu.202500014

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Updated at: 2025-08-19 12:30:16 +0900

Published on MDR: 2025-08-19 12:21:35 +0900

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