# Na<sub>3</sub>MgB<sub>37</sub>Si<sub>9</sub>: an icosahedral B<sub>12</sub> cluster framework containing {Si<sub>8</sub>} units

https://mdr.nims.go.jp/datasets/cedf9359-2007-4870-89dd-86a318cd752f

## File

- [H.Morito_Na3MgB37Si9.pdf](https://mdr.nims.go.jp/filesets/6f063eec-a1b4-4e41-9719-3c6f44db93da/download) ([Detail](https://mdr.nims.go.jp/filesets/6f063eec-a1b4-4e41-9719-3c6f44db93da.md))

## Id

cedf9359-2007-4870-89dd-86a318cd752f

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-11-14T03:18:32.557856Z

## Updated at

2024-11-21T07:35:21.773272Z

## Published at

2024-11-21T07:35:21.840936Z

## Doi



## First published url

https://doi.org/10.1107/s2056989022000494

## Date published

2022-02-01

## Recorded date published



## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: 'Na<sub>3</sub>MgB<sub>37</sub>Si<sub>9</sub>: an icosahedral B<sub>12</sub>
    cluster framework containing {Si<sub>8</sub>} units'
  title_type: original
  lang: en

## Description

- description: 新規ナトリウム-マグネシウムホウ化物ケイ化物Na3MgB37Si9の単結晶を合成した。空間群R3m（No. 166）で、格子定数はa
    = 10.1630(3) Å、c = 16.5742(6) Åである。この化合物ではMg原子がDy2.1B37Si9型構造の格子間位置に占有率0.5で存在する。B12正二十面体の(001)層がc軸方向に[-a/3,
    b/3, c/3]方向へずれながら積層し、B-Si結合と{Si8}ユニットを介して三次元フレームワーク構造を形成している。
  description_type: abstract
  lang: und

## Creator

- name: Haruhiko Morito
  role: author
- name: Takuji Ikeda
  role: author
- name: Yukari Katsura
  role: author
  orcid: https://orcid.org/0000-0002-8905-2995
- name: Hisanori Yamane
  role: author

## Contact agent



## Publisher

organization: International Union of Crystallography (IUCr)

## Managing organization



## Keyword

- subject: crystal structure;
  schema: not_defined
- subject: boron-rich boride
  schema: not_defined
- subject: sodium
  schema: not_defined
- subject: silicon
  schema: not_defined
- subject: single-crystal
  schema: not_defined
- subject: B2O3 flux
  schema: not_defined
- subject: crystal structure
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Acta Crystallographica Section E Crystallographic Communications
  issn: '20569890'
  volume: '78'
  issue: '2'
  start_page: 203
  end_page: 206

## Conference



## Related item



## Funding

- identifier: JPMJCR19J1
  funder_name: Japan Science and Technology Agency (JST) CREST
  description: Development of innovative functional materials based on large-scale
    search for new crystals

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 6f063eec-a1b4-4e41-9719-3c6f44db93da
  filename: H.Morito_Na3MgB37Si9.pdf
  content_type: application/pdf
  size: 527195
  md5: 49ff04a46691fd5111239d5d3e14d4c1

## Thumbnail

fileset_id: 6f063eec-a1b4-4e41-9719-3c6f44db93da
filename: H.Morito_Na3MgB37Si9.pdf