# Metal–organic framework adhesives with exceptionally high heat resistance

https://mdr.nims.go.jp/datasets/ce8505f3-fb41-4f08-ac68-a5f478484dc3

## File

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## Id

ce8505f3-fb41-4f08-ac68-a5f478484dc3

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-05-02T01:29:49.338822Z

## Updated at

2024-05-08T07:30:31.234100Z

## Published at

2024-05-08T07:30:31.318910Z

## Doi

https://doi.org/10.48505/nims.4500

## First published url

https://doi.org/10.1080/14686996.2024.2347193

## Date published

2024-12-31

## Recorded date published

2024-12-31

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Metal–organic framework adhesives with exceptionally high heat resistance
  title_type: original
  lang: en

## Description

- description: We synthesized high-heat-resistant adhesives based on metal – organic
    frameworks owing to their high decomposition temperature and the absence of a
    glass transition. Heat-resistance tests were performed on adhesive joints consisting
    of zeolitic imidazolate framework (ZIF)-67-based adhesives and a copper substrate.
    The as-synthesized ZIF-67-based adhesive exhibited heat resistances at 600 and
    700°C in air and nitrogen atmospheres, respectively, comparable to those of conventional
    high-heat-resistant polymer-based adhesives. The degradation mechanism of the
    ZIF-67 adhesives was investigated, and their high heat resistance was attributed
    to the stable existence of the ZIF-67 qtz phase in the adhesive layer at high
    temperatures without the formation of voids. Thus, adhesives based on ZIF-67 and
    other metal – organic frameworks can be applied in high-temperature industrial
    systems.
  description_type: abstract
  lang: en

## Creator

- name: Izuru Miyazaki
  role: author
  organization: Toyota Central R&D Labs. Inc
- name: Yumi Masuoka
  role: author
- name: Akitoshi Suzumura
  role: author
  organization: Malaysia–Japan International Institute of Technology
- name: Shinya Moribe
  role: author
- name: Hisaaki Takao
  role: author
- name: Mitsutaro Umehara
  role: author
  organization: Osaka University
  department: Department of Applied Chemistry, Graduate School of Engineering

## Contact agent



## Publisher

organization: Taylor & Francis

## Managing organization



## Keyword

- subject: Metal-organic framework
  schema: not_defined
- subject: structural adhesive
  schema: not_defined
- subject: heat resistance
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Science and Technology of Advanced Materials
  issn: '14686996'
  volume: '25'
  article_number: '2347193 '

## Conference



## Related item



## Funding



## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 6d3ba17b-b16e-4a5d-8e25-58ee8abf8607
  filename: Metal organic framework adhesives with exceptionally high heat resistance.pdf
  content_type: application/pdf
  size: 12581999
  md5: ced735a8a10319aaef7f2f229d702dcd

## Thumbnail

fileset_id: 6d3ba17b-b16e-4a5d-8e25-58ee8abf8607
filename: Metal organic framework adhesives with exceptionally high heat resistance.pdf