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説明:

Organic dyes showing absorbance and fluorescence in the near infrared and short-wave infrared regions are attractive for a variety of applications. Redox-coupled reversible switching of absorbance or fluorescence implies enhanced functionality of such dyes, especially where large changes in photophysical properties across the redox process can be realized. Here, the synthesis of two new pyrazinacenes containing four and five fused pyrazine units, appended with electron-donor triphenylamine groups, and redox-coupled switching of their photophysical properties is reported. In their reduced state, the compounds show absorbance and fluorescence in the visible region. Reversible shifts in absorbance and fluorescence from the visible to the near infrared or even short-wave infrared regions are observed upon chemical and electrochemical oxidations. Such large redox-coupled shifts in photophysical properties are unprecedented for a redox process that affects only a single, six-membered ring in which both reduced and oxidized states consist of neutral, closed-shell species. The compounds show high fluorescence quantum yields in their reduced states, and oxidized species show fluorescence quantum yields that compare well with existing near infrared and short-wave infrared active fluorescent dyes.

権利情報:

• Creative Commons BY Attribution 4.0 International
  

キーワード: Pyrazinacene, Acene, N-heteroacene, Redox-active

刊行年月日: 2025-03-20

出版者: Wiley

掲載誌:

• Angewandte Chemie International Edition (ISSN: 00448249) vol. 64 issue. 19 e202504564

研究助成金:

• Ministry of Education, Culture, Sports, Science and Technology
• Japan Society for the Promotion of Science London 21H01955

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1002/anie.202504564

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更新時刻: 2025-10-31 12:30:10 +0900

MDRでの公開時刻: 2025-10-31 12:24:38 +0900