# Ultra-stable and highly reactive colloidal gold nanoparticle catalysts protected using multi-dentate metal oxide nanoclusters

https://mdr.nims.go.jp/datasets/cc4548a1-7abb-41fa-9f59-ecdbfe56fb26

## File

- [s41467-024-45066-9.pdf](https://mdr.nims.go.jp/filesets/ea4d66a7-975e-42e9-92c9-5bd2f1e13cab/download) ([Detail](https://mdr.nims.go.jp/filesets/ea4d66a7-975e-42e9-92c9-5bd2f1e13cab.md))

## Id

cc4548a1-7abb-41fa-9f59-ecdbfe56fb26

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-11-26T07:05:20.719422Z

## Updated at

2024-11-28T07:30:25.669233Z

## Published at

2024-11-28T07:30:25.895717Z

## Doi



## First published url

https://doi.org/10.1038/s41467-024-45066-9

## Date published

2024-02-06

## Recorded date published



## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Ultra-stable and highly reactive colloidal gold nanoparticle catalysts protected
    using multi-dentate metal oxide nanoclusters
  title_type: original
  lang: en

## Description

- description: Owing to their remarkable properties, gold nanoparticles are applied
    in diverse fields, including catalysis, electronics, energy conversion and sensors.
    However, for catalytic applications of colloidal gold nanoparticles, the trade-off
    between their reactivity and stability is a significant concern. Here we report
    a universal approach for preparing stable and reactive colloidal small (~3 nm)
    gold nanoparticles by using multi-dentate polyoxometalates as protecting agents
    in non-polar solvents. These nanoparticles exhibit exceptional stability even
    under conditions of high concentration, long-term storage, heating and addition
    of bases. Moreover, they display excellent catalytic performance in various oxidation
    reactions of organic substrates using molecular oxygen as the sole oxidant. Our
    findings highlight the ability of inorganic multi-dentate ligands with structural
    stability and robust steric and electronic effects to confer stability and reactivity
    upon gold nanoparticles. This approach can be extended to prepare metal nanoparticles
    other than gold, enabling the design of novel nanomaterials with promising applications.
  description_type: abstract
  lang: und

## Creator

- name: Kang Xia
  role: author
  orcid: https://orcid.org/0000-0002-9376-8953
- name: Takafumi Yatabe
  role: author
  orcid: https://orcid.org/0000-0001-5504-4762
- name: Kentaro Yonesato
  role: author
- name: Soichi Kikkawa
  role: author
- name: Seiji Yamazoe
  role: author
  orcid: https://orcid.org/0000-0002-8382-8078
- name: Ayako Nakata
  role: author
  orcid: https://orcid.org/0000-0002-3311-6283
- name: Ryo Ishikawa
  role: author
  orcid: https://orcid.org/0000-0001-5801-0971
- name: Naoya Shibata
  role: author
  orcid: https://orcid.org/0000-0003-3548-5952
- name: Yuichi Ikuhara
  role: author
  orcid: https://orcid.org/0000-0003-3886-005X
- name: Kazuya Yamaguchi
  role: author
  orcid: https://orcid.org/0000-0002-7661-4936
- name: Kosuke Suzuki
  role: author
  orcid: https://orcid.org/0000-0002-8123-1462

## Contact agent



## Publisher

organization: Springer Science and Business Media LLC

## Managing organization



## Keyword

- subject: gold nanoparticles
  schema: not_defined
- subject: multi-dentate metal oxide nanoclusters
  schema: not_defined
- subject: colloidal gold nanoparticle catalysts
  schema: not_defined
- subject: polyoxometalates
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Nature Communications
  issn: '20411723'
  volume: '15'
  article_number: '851'

## Conference



## Related item



## Funding

- identifier: JPMJPR18T7
  funder_name: MEXT | JST | Precursory Research for Embryonic Science and Technology
- identifier: JPMJPR227A
  funder_name: MEXT | JST | Precursory Research for Embryonic Science and Technology
- identifier: JPMJPR19T9
  funder_name: MEXT | JST | Precursory Research for Embryonic Science and Technology
- identifier: KAKENHI 22H04971
  funder_name: MEXT | Japan Society for the Promotion of Science
- identifier: JPMJPR20T4
  funder_name: MEXT | JST | Precursory Research for Embryonic Science and Technology
- identifier: JPMJFR213M
  funder_name: MEXT | Japan Science and Technology Agency
- identifier: JPMJFR2033
  funder_name: MEXT | Japan Science and Technology Agency

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: ea4d66a7-975e-42e9-92c9-5bd2f1e13cab
  filename: s41467-024-45066-9.pdf
  content_type: application/pdf
  size: 3159686
  md5: 327c3e04fda77ab6c7e1484325a3ad90

## Thumbnail

fileset_id: ea4d66a7-975e-42e9-92c9-5bd2f1e13cab
filename: s41467-024-45066-9.pdf