# Tetracene Inclusion in Boron Nitride Nanotubes for Photoluminescence Property Modulation Based on Aggregated State Control in Their Nanocavity https://mdr.nims.go.jp/datasets/c62cca91-23e2-4869-b5da-aa8964ffa91e ## File - [著者最終版.pdf](https://mdr.nims.go.jp/filesets/1d4aab4b-711a-4eb8-ad6d-cc97392b81b1/download) ([Detail](https://mdr.nims.go.jp/filesets/1d4aab4b-711a-4eb8-ad6d-cc97392b81b1.md)) ## Id c62cca91-23e2-4869-b5da-aa8964ffa91e ## Local identifier ## Visibility open_to_public ## State published ## Created at 2025-08-01T08:08:52.602761Z ## Updated at 2025-08-03T23:57:45.911588Z ## Published at 2026-07-23T23:28:17.424976Z ## Doi https://doi.org/10.48505/nims.5623 ## First published url https://doi.org/10.1021/acs.jpclett.5c01618 ## Date published 2025-07-31 ## Recorded date published 2025-7-31 ## Resource type journal_article ## Manuscript type accepted_manuscript ## Collection ## Title - title: Tetracene Inclusion in Boron Nitride Nanotubes for Photoluminescence Property Modulation Based on Aggregated State Control in Their Nanocavity title_type: original lang: en ## Description - description: " Boron nitride nanotubes (BNNTs) are used for the self-assembly of tetracene (Tc) molecules without chemical modification in their one-dimensional nanocavities. The Tc aggregated state can be changed depending on the encapsulated Tc amount that is controlled by the sublimation condition of Tc molecules for the complexation (Tc@BNNTs). As a result, the photophysical processes including singlet fission in the Tc assemblies are varied, which enables the emission mode switching of the aggregation-based fluorescence and the excimer emission for Tc@BNNTs. Consequently, the host–guest complexation using BNNTs allows not only the fabrication and evaluation of optically functionalized molecular assemblies in the nanocavity but also the modulation of their photophysical processes, by which the emission colors of Tc@BNNTs are also tuned." description_type: abstract lang: und ## Creator - name: Hayato Saeki role: author orcid: https://orcid.org/0000-0001-9072-8414 - name: Takumi Ehara role: author orcid: https://orcid.org/0009-0002-2169-8236 - name: Kiyoshi Miyata role: author orcid: https://orcid.org/0000-0001-6748-1337 - name: Toshikazu Ono role: author orcid: https://orcid.org/0000-0001-5427-8540 - name: Satoru Emoto role: author - name: Hiroki Ago role: author orcid: https://orcid.org/0000-0003-0908-5883 - name: Aki Masaoka role: author - name: Yoichi Sasaki role: author orcid: https://orcid.org/0000-0002-0619-7970 - name: Koji Harano role: author orcid: https://orcid.org/0000-0001-6800-8023 - name: Koji Kimoto role: author orcid: https://orcid.org/0000-0002-3927-0492 - name: Tsuyohiko Fujigaya role: author orcid: https://orcid.org/0000-0003-3563-8234 - name: Tomohiro Shiraki role: author orcid: https://orcid.org/0000-0002-6604-9662 ## Contact agent ## Publisher organization: American Chemical Society (ACS) ## Managing organization ## Keyword - subject: photoluminescence schema: not_defined - subject: transmission electron microscopy schema: not_defined - subject: host-guest chemistry schema: not_defined - subject: boron nitride nanotubes schema: not_defined ## Rights - description: This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Physical Chemistry Letters, copyright © 2025 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpclett.5c01618. identifier: http://rightsstatements.org/vocab/InC/1.0/ ## Other identifier(s) ## Data origin - data_origin_type: other ## Embargo start_date: 2025-07-24 end_date: 2026-07-24 ## Journal - title: The Journal of Physical Chemistry Letters issn: '19487185' volume: '16' issue: '30' start_page: 7738 end_page: 7743 ## Conference ## Related item ## Funding - identifier: JPMXP1222KU1007 funder_name: Ministry of Education, Culture, Sports, Science and Technology - funder_name: Japan Association for Chemical Innovation - funder_name: Toyota Physical and Chemical Research Institute - identifier: JPMJCR20B1 funder_name: Core Research for Evolutional Science and Technology - funder_name: Kyushu University - identifier: JPMJAX24D8 funder_name: ACT-X - identifier: JP21H05232 funder_name: Japan Society for the Promotion of Science - identifier: JP21H05233 funder_name: Japan Society for the Promotion of Science - identifier: JP22H01910 funder_name: Japan Society for the Promotion of Science - identifier: JP22H02159 funder_name: Japan Society for the Promotion of Science - identifier: JP23H03833 funder_name: Japan Society for the Promotion of Science - identifier: JP23H04874 funder_name: Japan Society for the Promotion of Science - identifier: JP23K17863 funder_name: Japan Society for the Promotion of Science - identifier: JP23K23178 funder_name: Japan Society for the Promotion of Science - identifier: JP23K23427 funder_name: Japan Society for the Promotion of Science - identifier: JP24H00407 funder_name: Japan Society for the Promotion of Science - identifier: JP24K01471 funder_name: Japan Society for the Promotion of Science - identifier: JP24K01515 funder_name: Japan Society for the Promotion of Science - identifier: JP24K17745 funder_name: Japan Society for the Promotion of Science - identifier: JPMJSP2136 funder_name: Support for Pioneering Research Initiated by the Next Generation ## Instrument ## Instrument operator ## Instrument managing organization ## Measurement method ## Specimen ## Chemical composition ## Structure for specimen ## Structural feature for specimen ## Specific property for specimen ## Process for specimen treatment ## Computational method ## Energy level/transition state ## Software ## Custom property ## Fileset - id: 1d4aab4b-711a-4eb8-ad6d-cc97392b81b1 filename: 著者最終版.pdf content_type: application/pdf size: 2342952 md5: 22b9061b079ae388c4d2bcfef3cdd7ab ## Thumbnail fileset_id: 1d4aab4b-711a-4eb8-ad6d-cc97392b81b1 filename: 著者最終版.pdf