# Current State and Perspectives of Exfoliated Zeolites

https://mdr.nims.go.jp/datasets/c0ae0264-83fa-4390-b14e-aec5f2210c4b

## File

- [Advanced Materials - 2023 - Roth - Current State and Perspectives of Exfoliated Zeolites.pdf](https://mdr.nims.go.jp/filesets/9c0ea6f9-54a3-48d0-8b2c-f4945b6acbcf/download) ([Detail](https://mdr.nims.go.jp/filesets/9c0ea6f9-54a3-48d0-8b2c-f4945b6acbcf.md))

## Id

c0ae0264-83fa-4390-b14e-aec5f2210c4b

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-07-09T01:16:46.819686Z

## Updated at

2024-07-09T03:30:33.146499Z

## Published at

2024-07-09T03:30:33.219040Z

## Doi



## First published url

https://doi.org/10.1002/adma.202307341

## Date published

2023-11-28

## Recorded date published

2024-1

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Current State and Perspectives of Exfoliated Zeolites
  title_type: original
  lang: en

## Description

- description: "Zeolites are highly efficient industrial catalysts and sorbents with
    microporous\r\nframework structures. Approximately 10% of the frameworks, but
    eventually\r\nall in the long run, have produced both 3D crystals and 2D layers.
    The latter\r\ncan be intercalated and expanded like all 2D materials but proved
    difficult to\r\nexfoliate directly into suspensions of monolayers in solution
    as precursors for\r\nunique synthetic opportunities. Successful exfoliations have
    been reported\r\nrecently and are overviewed in this perspective article. The
    discussion\r\nhighlights 3 primary challenges in this field, namely finding suitable
    2D zeolite\r\npreparations that exfoliate directly in high yield, proving uniform
    layer\r\nthickness in solution and identifying applications to exploit the unique\r\nsynthetic
    capabilities and properties of exfoliated zeolite monolayers. Four\r\nzeolites
    have been confirmed to exfoliate directly into monolayers: 3 with\r\nknown structures—MWW,
    MFI, and RWR and one unknown, bifer with a unit\r\ncell close to ferrierite. The
    exfoliation into monolayers is confirmed by the\r\ncombination of 5–6 characterization
    techniques including AFM, in situ and\r\nin-plane XRD, and microscopies. The promising
    areas of development are\r\noriented films and membranes, intimately mixed zeolite
    phases, and\r\nhierarchical nanoscale composites with other active species like
    nanoparticles\r\nand clusters that are unfeasible by solid state processes."
  description_type: abstract
  lang: eng

## Creator

- name: Wieslaw J. Roth
  role: author
  organization: Jagiellonian University
- name: Maksym Opanasenko
  role: author
  organization: Charles University in Prague
- name: Michal Mazur
  role: author
  organization: Charles University in Prague
- name: Barbara Gil,
  role: author
  organization: Jagiellonian University
- name: Jiˇrí ˇCejka
  role: author
  organization: Charles University in Prague
- name: Takayoshi Sasaki
  role: author
  orcid: https://orcid.org/0000-0002-2872-0427
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26

## Contact agent



## Publisher

organization: Wiley-Blackwell

## Managing organization



## Keyword

- subject: bifer
  schema: not_defined
- subject: chemical exfoliation
  schema: not_defined
- subject: ilerite
  schema: not_defined
- subject: nanocomposites
  schema: not_defined
- subject: ultrathin zeolite nanosheets
  schema: not_defined
- subject: zeolite films
  schema: not_defined
- subject: zeolites MFI and MWW
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by-nc-nd/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: ADVANCED MATERIALS
  issn: '15214095'
  volume: '36'
  issue: '4'

## Conference



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## Instrument



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## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



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## Fileset

- id: 9c0ea6f9-54a3-48d0-8b2c-f4945b6acbcf
  filename: Advanced Materials - 2023 - Roth - Current State and Perspectives of Exfoliated
    Zeolites.pdf
  content_type: application/pdf
  size: 3776475
  md5: 7d52d3cfce927ce39e8cfaff8daa7c07

## Thumbnail

fileset_id: 9c0ea6f9-54a3-48d0-8b2c-f4945b6acbcf
filename: Advanced Materials - 2023 - Roth - Current State and Perspectives of Exfoliated
  Zeolites.pdf