# Electrochemical Stability of Li<sub>5.4</sub>(PS<sub>4</sub>)(S<sub>0.4</sub>Cl<sub>1.0</sub>Br<sub>0.6</sub>) in an All-Solid-State Battery Comprising LiNbO<sub>3</sub>-Coated Li(Ni<sub>0.8</sub>Co<sub>0.1</sub>Mn<sub>0.1</sub>)O<sub>2</sub> Cathode and Lithium Metal Anode

https://mdr.nims.go.jp/datasets/bd4052f5-1362-4a23-8326-bc3635edf835

## File

- [20230808_ECS_main_revision_v5_for_MDR.docx](https://mdr.nims.go.jp/filesets/478e8073-a2c0-4871-9ca5-45815552f8f0/download) ([Detail](https://mdr.nims.go.jp/filesets/478e8073-a2c0-4871-9ca5-45815552f8f0.md))

## Id

bd4052f5-1362-4a23-8326-bc3635edf835

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2023-10-30T07:51:33.993397Z

## Updated at

2024-12-04T05:52:57.178364Z

## Published at

2024-12-04T05:52:57.258315Z

## Doi

https://doi.org/10.48505/nims.5085

## First published url

https://doi.org/10.1149/1945-7111/acf880

## Date published

2023-09-01

## Recorded date published

2023-9-1

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Electrochemical Stability of Li<sub>5.4</sub>(PS<sub>4</sub>)(S<sub>0.4</sub>Cl<sub>1.0</sub>Br<sub>0.6</sub>)
    in an All-Solid-State Battery Comprising LiNbO<sub>3</sub>-Coated Li(Ni<sub>0.8</sub>Co<sub>0.1</sub>Mn<sub>0.1</sub>)O<sub>2</sub>
    Cathode and Lithium Metal Anode
  title_type: original
  lang: en

## Description

- description: All-solid-state lithium-ion batteries are a promising next-generation
    technology because they have higher energy densities than their liquid-electrolyte
    counterparts. Recently, halogen-rich argyrodite, specifically Li5.4(PS4)(S0.4Cl1.0Br0.6),
    has been reported to show higher ionic conductivities than other sulfides with
    argyrodite structures and electrochemical stability against lithium metal. However,
    the stability of Li5.4(PS4)(S0.4Cl1.0Br0.6) against cathode active materials in
    all-solid-state batteries has not yet been evaluated. Herein, we report the electrochemical
    stability of Li5.4(PS4)(S0.4Cl1.0Br0.6) as a solid electrolyte in an all-solid-state
    battery.
  description_type: abstract
  lang: eng

## Creator

- name: Naoya Masuda
  role: author
  orcid: https://orcid.org/0000-0002-1259-7460
  organization: National Institute for Materials Science
- name: Kiyoshi Kobayashi
  role: author
  orcid: https://orcid.org/0000-0001-9644-1879
  organization: National Institute for Materials Science
- name: Futoshi Utsuno
  role: author
- name: Naoaki Kuwata
  role: author
  orcid: https://orcid.org/0000-0002-0736-6967
  organization: National Institute for Materials Science

## Contact agent



## Publisher

organization: The Electrochemical Society

## Managing organization



## Keyword

- subject: Argyrodite
  schema: not_defined
- subject: Solid-state lithium-ion batteries
  schema: not_defined

## Rights

- description: This is the Accepted Manuscript version of an article accepted for
    publication in ournal of The Electrochemical Society.  IOP Publishing Ltd is not
    responsible for any errors or omissions in this version of the manuscript or any
    version derived from it.  The Version of Record is available online at https://doi.org/10.1149/1945-7111/acf880.
  identifier: https://creativecommons.org/licenses/by-nc-nd/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2023-09-21
end_date: 2024-09-21

## Journal

- title: Journal of The Electrochemical Society
  issn: '00134651'
  volume: '170'
  issue: '9'
  article_number: '090529'

## Conference



## Related item



## Funding



## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 478e8073-a2c0-4871-9ca5-45815552f8f0
  filename: 20230808_ECS_main_revision_v5_for_MDR.docx
  content_type: application/vnd.openxmlformats-officedocument.wordprocessingml.document
  size: 781395
  md5: 22662f3c0393af721730c7efcbb924fb

## Thumbnail

fileset_id: 478e8073-a2c0-4871-9ca5-45815552f8f0
filename: 20230808_ECS_main_revision_v5_for_MDR.docx