# Hybrid Multiferroic Behavior in the Double Perovskite (Ca<sub>0.5</sub>Mn<sub>1.5</sub>)MnWO<sub>6</sub>

https://mdr.nims.go.jp/datasets/bb66e54f-b27d-4a92-847a-6119e9d51a02

## File

- [ESI-Ca05Mn15MnWO6-160724.pdf](https://mdr.nims.go.jp/filesets/7bcbf0d7-17d6-4f93-bcce-0ff2a0c7c117/download) ([Detail](https://mdr.nims.go.jp/filesets/7bcbf0d7-17d6-4f93-bcce-0ff2a0c7c117.md))
- [Ca05Mn15MnWO6-16-07-2024-clean.pdf](https://mdr.nims.go.jp/filesets/7b1d24fd-05fc-47ad-a18e-a4652bdefbbb/download) ([Detail](https://mdr.nims.go.jp/filesets/7b1d24fd-05fc-47ad-a18e-a4652bdefbbb.md))

## Id

bb66e54f-b27d-4a92-847a-6119e9d51a02

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-08-16T04:55:55.285978Z

## Updated at

2025-08-12T23:30:23.167961Z

## Published at

2025-08-12T23:17:18.977599Z

## Doi

https://doi.org/10.48505/nims.4663

## First published url

https://doi.org/10.1021/acs.chemmater.4c01720

## Date published

2024-08-13

## Recorded date published

2024-8-13

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Hybrid Multiferroic Behavior in the Double Perovskite (Ca<sub>0.5</sub>Mn<sub>1.5</sub>)MnWO<sub>6</sub>
  title_type: original
  lang: en

## Description

- description: Multiferroic materials with ordered electric dipoles and magnetic spins
    attract a lot of attention from viewpoints of applications and fundamental science.
    Multiferroics are generally classified into type-I, where (anti)ferroelectric
    and magnetic transitions are well separated and have completely different origins,
    and type-II, where magnetic structures break crystallographic inversion symmetry.
    Type-III multiferroics were recently introduced, which are close to type-I, but
    they do not show non-polar-to-polar structural transitions as polar structures
    are fixed by chemical order. In this work, we describe dielectric and magnetic
    behaviors observed in the double perovskites, (Ca0.5Mn1.5)MnWO6 and (Ca0.3Mn1.7)MnWO6,
    crystallizing in space group P21/n. Dielectric constant of these compounds showed
    a peak at TC = 22 K and TC = 27 K, respectively, and followed the Curie-Weiss
    law in wide temperature ranges between TC and 300 K, where TC is an (anti)ferroelectric
    transition temperature – this behavior is typical for type-I multiferroics with
    proper (anti)ferroelectric transitions. At the same time, TC matches with the
    Neel temperature TN – this behavior is typical for type-II multiferroics. Therefore,
    materials with such behavior can be called hybrid multiferroics.
  description_type: abstract
  lang: und

## Creator

- name: Alexei A. Belik
  role: author
  orcid: https://orcid.org/0000-0001-9031-2355
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: double perovskites
  schema: not_defined
- subject: multiferroics
  schema: not_defined
- subject: Curie-Weiss
  schema: not_defined
- subject: dielectric properties
  schema: not_defined

## Rights

- description: This document is the Accepted Manuscript version of a Published Work
    that appeared in final form in The Journal of Physical Chemistry Letters, copyright
    © 2024 American Chemical Society after peer review and technical editing by the
    publisher. To access the final edited and published work see https://doi.org/10.1021/acs.chemmater.4c01720
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-08-13
end_date: 2025-08-13

## Journal

- title: CHEMISTRY OF MATERIALS
  issn: '15205002'
  start_page: 7604
  end_page: 7609

## Conference



## Related item



## Funding

- identifier: 2022-11
  funder_name: Kazuchika Okura Memorial Foundation
- identifier: JP22H04601
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 7bcbf0d7-17d6-4f93-bcce-0ff2a0c7c117
  filename: ESI-Ca05Mn15MnWO6-160724.pdf
  content_type: application/pdf
  size: 581555
  md5: a1bc7c30ce3084ac248a5b90d56d02ed
- id: 7b1d24fd-05fc-47ad-a18e-a4652bdefbbb
  filename: Ca05Mn15MnWO6-16-07-2024-clean.pdf
  content_type: application/pdf
  size: 1383954
  md5: 221b112fb72468069a1154f66699d61a

## Thumbnail

fileset_id: 7bcbf0d7-17d6-4f93-bcce-0ff2a0c7c117
filename: ESI-Ca05Mn15MnWO6-160724.pdf