# Bridging classical concepts and modern advances in electrode processes: a tutorial review

https://mdr.nims.go.jp/datasets/ba232625-f7ff-4633-ae1b-88cf14ebc758

## File

- [Manuscript-tutorial review_PCCP_revised final_clean.pdf](https://mdr.nims.go.jp/filesets/e8222457-262a-463c-a749-f2ae326edbe5/download) ([Detail](https://mdr.nims.go.jp/filesets/e8222457-262a-463c-a749-f2ae326edbe5.md))

## Id

ba232625-f7ff-4633-ae1b-88cf14ebc758

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-12-14T22:11:45.723443Z

## Updated at

2026-04-30T03:01:11.491392Z

## Published at

2026-11-06T08:04:45.014760Z

## Doi

https://doi.org/10.48505/nims.6011

## First published url

https://doi.org/10.1039/D5CP03949E

## Date published

2025-11-06

## Recorded date published

2025-12-10

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: 'Bridging classical concepts and modern advances in electrode processes:
    a tutorial review'
  title_type: original
  lang: en

## Description

- description: Electrochemistry is becoming increasingly crucial due to its central
    role in energy conversion/storage and the production of high-value chemicals via
    renewable energy. As these technologies advance, students and researchers, particularly
    those entering the field from adjacent disciplines, are confronted with the intricate
    physicochemical phenomena at electrode–electrolyte interfaces, whose fundamental
    understanding is essential for the rational design of efficient, selective, and
    robust electrocatalytic systems. In addition, several simple and practical methods
    have been developed in recent years to try to address the existing stability issues
    in electrocatalysis. Aiming to link the multifaceted history of electrochemistry
    with its promising future for diverse applications, in this Tutorial Review, which
    focuses on electrode processes, starting from a brief history, we provide representative
    discussion on microkinetic modelling with/without the assumption of the rate-determining
    step, demonstrate mass transport effects by reactants/products, analyse electrode
    material reconstruction, and explore microkinetic models for depicting degradation
    processes. An alternative perspective on reaction mechanisms is presented based
    on graph theory. Next, we introduce a data-driven approach to facilitate the understanding
    of electrode reactions including both activity description and stability issue.
    Finally, we propose a heuristic framework via a matrix to organise electrode states
    in electrode processes. We hope this Tutorial Review will provide fundamental
    and useful insights into processes at the electrified electrode–electrolyte interface,
    inspiring the rational design of highly efficient electrochemical reactions for
    green chemistry in the near future.
  description_type: abstract
  lang: en

## Creator

- name: Miao Wang
  role: author
  orcid: https://orcid.org/0000-0001-9483-6877
  organization: National Institute for Materials Science
- name: Ken Sakaushi
  role: author
  orcid: https://orcid.org/0000-0003-4797-9087
  organization: National Institute for Materials Science

## Contact agent



## Publisher

organization: Royal Society of Chemistry (RSC)

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## Keyword

- subject: electrode process
  schema: not_defined
- subject: microscopic mechanism
  schema: not_defined
- subject: electrified solid-liquid interface
  schema: not_defined

## Rights

- identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2025-11-06
end_date: 2026-11-06

## Journal

- title: Physical Chemistry Chemical Physics
  issn: '14639076'
  volume: '27'
  issue: '48'
  start_page: 25743
  end_page: 25766

## Conference



## Related item



## Funding

- identifier: JPMXP1122712807
  funder_name: Ministry of Education, Culture, Sports, Science and Technology
- identifier: GteX Program JPMJGX23H2
  funder_name: Japan Science and Technology Agency

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## Fileset

- id: e8222457-262a-463c-a749-f2ae326edbe5
  filename: Manuscript-tutorial review_PCCP_revised final_clean.pdf
  content_type: application/pdf
  size: 1840788
  md5: bd58b8045c6d86429a93a181c1158172

## Thumbnail

fileset_id: e8222457-262a-463c-a749-f2ae326edbe5
filename: Manuscript-tutorial review_PCCP_revised final_clean.pdf