# Construction of Heterometallic Coordination Nanosheets Comprising Both Inert and Labile Metal Ions Together via Metalloligand Approach

https://mdr.nims.go.jp/datasets/b7f7a249-ba4f-457d-86ef-51e775c86423

## Files

- [bera-et-al-2025-construction-of-heterometallic-coordination-nanosheets-comprising-both-inert-and-labile-metal-ions.pdf](https://mdr.nims.go.jp/filesets/7d9c001a-648e-4c9f-9d02-96c350a397fd/download) ([Detail](https://mdr.nims.go.jp/filesets/7d9c001a-648e-4c9f-9d02-96c350a397fd.md))

## Id

b7f7a249-ba4f-457d-86ef-51e775c86423

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-12-31T12:09:03.149598Z

## Updated at

2026-01-05T23:59:31.846853Z

## Published at

2026-01-06T03:19:35.470779Z

## Doi



## First published url

https://doi.org/10.1021/acs.inorgchem.5c00224

## Date published

2025-05-12

## Recorded date published

2025-5-12

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Construction of Heterometallic Coordination Nanosheets Comprising Both Inert
    and Labile Metal Ions Together via Metalloligand Approach
  title_type: original
  lang: en

## Description

- description: " Construction of coordination nanosheets (CONASHs) containing both
    inert and labile metal ions together is fundamentally significant but remains
    synthetically unachievable until now and difficult to realize via conventional
    synthetic approach of CONASHs due to variable complexation conditions between
    heterometal ions and organic ligands. Here, we demonstrate a strategy to harness
    both inert and labile metal ions together into a CONASHs structure by introducing
    the concept of a metalloligand. Metalloligands comprising inert metal ion (Os2+.
    /Ru 2+) and free coordinating sites are designed and synthesized and can be further
    used as coordinating ligand to bind labile heterometal ion (Fe 2+ ) for building
    of heterometallic CONASHs (HMCONASHs). Following this, two HMCONASHs containing
    homoleptic heterometallic complexes are constructed that show broad absorption
    and electrochemical window with reversible dual redox activity. Further, HMCONASH
    films exhibit multicolor electrochromism at different voltages, indicating their
    potential for various applications. This synthetic approach may open a window
    to create CONASHs with diverse structures and functions that are hard to achieve
    via a traditional synthetic approach."
  description_type: abstract
  lang: und

## Creator

- name: Manas K. Bera
  role: author
  orcid: https://orcid.org/0000-0003-4784-9530
  organization: National Institute for Materials Science
- name: Sanjib Sarmah
  role: author
- name: Atanu Maity
  role: author
- name: Masayoshi Higuchi
  role: author
  orcid: https://orcid.org/0000-0001-9877-1134
  organization: National Institute for Materials Science

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: Coordination Nanosheets
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/
  date_licensed: 2025-04-03

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Inorganic Chemistry
  issn: 1520510X
  volume: '64'
  issue: '18'
  start_page: 8837
  end_page: 8844

## Conference



## Related item



## Funding

- identifier: JPMJMI21I4
  funder_name: JST-Mirai Program
- identifier: DST/INSPIRE/04/2019/000999 - GAP 0873
  funder_name: Department of Science and Technology, Ministry of Science and Technology,
    India
- identifier: JPMEERF20221M02
  funder_name: Environmental Restoration and Conservation Agency

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



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## Fileset

- id: 7d9c001a-648e-4c9f-9d02-96c350a397fd
  filename: bera-et-al-2025-construction-of-heterometallic-coordination-nanosheets-comprising-both-inert-and-labile-metal-ions.pdf
  content_type: application/pdf
  size: 11046939
  md5: 4d0b36bd8906da3be50424f0188e9e08

## Thumbnail

fileset_id: 7d9c001a-648e-4c9f-9d02-96c350a397fd
filename: bera-et-al-2025-construction-of-heterometallic-coordination-nanosheets-comprising-both-inert-and-labile-metal-ions.pdf