Article Tunable photo-induced electronic property of octahedral metal clusters

Thi Kim Ngan Nguyen ORCID ; Fabien Grasset ; Noée Dumait ; Stéphane Cordier ; David Berthebaud ; Naoki Ohashi SAMURAI ORCID ; Tetsuo Uchikoshi SAMURAI ORCID

Collection

Citation
Thi Kim Ngan Nguyen, Fabien Grasset, Noée Dumait, Stéphane Cordier, David Berthebaud, Naoki Ohashi, Tetsuo Uchikoshi. Tunable photo-induced electronic property of octahedral metal clusters. Materials Letters: X. 2021, 11 (), 100079.

Description:

(abstract)

The tunable photo-induced electronic property of the Cs2[{Mo6Bri8}Bra6] and Br2[{Ta6Bri12}(H2O)a6] octahedral metal cluster-based compounds was characterized by the zeta potential measurement upon irradiation by ultraviolet–visible (UV–Vis) light. The enhancement of the electronic charge on the surface of the [{Mo6Bri8}Bra6]2- cluster-based anion caused by the irradiation increased the negative zeta potential. Both compounds showed the dependence of the zeta potential as a function of the light excitation. This will be a promising property for sensor applications based on the reversibility of the photo-electrochemical properties of the functional cluster.

Rights:

Keyword: Metal cluster, Zeta potential, Optoelectronic property , Molybdenum Tantalum

Date published: 2021-04-25

Publisher: Elsevier BV

Journal:

  • Materials Letters: X (ISSN: 25901508) vol. 11 100079

Funding:

Manuscript type: Publisher's version (Version of record)

MDR DOI:

First published URL: https://doi.org/10.1016/j.mlblux.2021.100079

Related item:

Other identifier(s):

Contact agent:

Updated at: 2025-04-14 09:47:10 +0900

Published on MDR: 2025-04-14 14:56:24 +0900

Filename Size
Filename 1-s2.0-S259015082100020X-main.pdf (Thumbnail)
application/pdf
Size 1 MB Detail