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説明:

Because lithium dendrite deposition during charging and discharging of all solid-state batteries (ASSLBs) is an important difficulty leading to deactivation, precise analysis of the lithium state is indispensable. We explored the potential use of hard-carbon (HC) for an ASSLB anode using operando 7Li NMR to investigate lithium behavior. Cells using circular electrodes capable of applying constraint pressure to the electrode material were fabricated to achieve precise operando NMR measurements for sulfur-based ASSLBs. Adsorption and desorption behaviors of lithium in HC were found to be nearly identical to those of HC in liquid LIBs. However, short circuits occurred after several hours of constant current overlithiation or potential holding at −5.5 mV although no clear amplification of Li dendrite signal was observed. Signal components attributable to quasimetallic clusters were observed in both cases, which suggests that lithium can form clusters in open pores or on the HC surface during overlithiation. Clusters in the open pores or surface can conduct electricity and may serve as nucleation sites for dendrite growth. Although the use of HC anodes can suppress dendrite formation in ASSLBs, more precise voltage control is required than that used for liquid LIBs.

権利情報:

• Creative Commons BY-NC Attribution-NonCommercial 4.0 International
  

キーワード: operand nmr

刊行年月日: 2025-11-07

出版者: Elsevier BV

掲載誌:

• Journal of Power Sources (ISSN: 03787753) vol. 662 238755

研究助成金:

• American Theological Library Association JPJ004596
• Japan Society for the Promotion of Science 23K04535

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1016/j.jpowsour.2025.238755

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更新時刻: 2026-01-09 10:15:02 +0900

MDRでの公開時刻: 2026-01-09 12:22:32 +0900