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説明:

We report structures of polycrystalline frameworks by uncovering the coexistence of different morphologies and their static and dynamic behaviors, disclosing a realistic picture and multiple-scale insights into structures of the most frequently used polycrystalline frameworks. Visualization with high-resolution transmission electron microscopy revealed four distinct morphologies, i.e., nanoparticle aggregates, nanorod aggregates, ultrathin nanosheets, and parasitic fusion entities. Moreover, direct visualization revealed the existence of different polygons and channels and their contents together with their boundaries and unstructured complements.

権利情報:

• In Copyright
  

  This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © 2025 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work seehttps://doi.org/10.1021/jacs.5c09081.

キーワード: covalent organic framework, transmission electron microscopy

刊行年月日: 2025-07-30

出版者: American Chemical Society

掲載誌:

• Journal of the American Chemical Society (ISSN: 00027863) vol. 147 issue. 30 p. 26955-26968

研究助成金:

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5800

公開URL: https://doi.org/10.1021/jacs.5c09081

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更新時刻: 2025-10-09 11:28:57 +0900

MDRでの公開時刻: 2026-07-18 08:27:29 +0900