# Correlation between Electrolyte Concentration and Lithium Morphology during Lithium Bis(fluorosulfonyl)amide–Tetraglyme Electrolyte Deposition–Dissolution Reactions

https://mdr.nims.go.jp/datasets/aa34b8d7-ddf0-44c1-b40e-6d9dd27ad6b4

## File

- [JES Revised Manuscript.docx](https://mdr.nims.go.jp/filesets/78ace0a1-c8e5-4323-af83-a35a2204e10d/download) ([Detail](https://mdr.nims.go.jp/filesets/78ace0a1-c8e5-4323-af83-a35a2204e10d.md))

## Id

aa34b8d7-ddf0-44c1-b40e-6d9dd27ad6b4

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-10-15T05:52:36.828699Z

## Updated at

2025-10-21T06:51:14.236953Z

## Published at

2025-10-21T06:43:04.398405Z

## Doi

https://doi.org/10.48505/nims.4858

## First published url

https://doi.org/10.1149/1945-7111/ad803d

## Date published

2024-10-01

## Recorded date published

2024-10-1

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Correlation between Electrolyte Concentration and Lithium Morphology during
    Lithium Bis(fluorosulfonyl)amide–Tetraglyme Electrolyte Deposition–Dissolution
    Reactions
  title_type: original
  lang: en

## Description

- description: Electrodeposition and chemical dissolution reactions of Li are strongly
    affected by the electrolyte concentration at the electrode surface. In this study,
    we investigated the processes involved in the formation of Li deposits at various
    electrolyte concentrations and different numbers of deposition–dissolution cycles.
    Growth of the deposits during the cycles was assessed using a digital microscope.
    The thickness of the fibrous layer was strongly dependent on the electrolyte solute–solvent
    molar ratio. The thickness of the fibrous layer increased as the number of cycles
    increased when the electrolyte solute–solvent molar ratio was low but decreased
    when the molar ratio was high. Temporal changes in the electrolyte concentration
    and in the diffusion layers near the electrode were identified using a laser interference
    microscope. The results led us to conclude that there are three fibrous Li deposit
    growth models that occur at different solvent–solute molar ratios.
  description_type: abstract
  lang: und

## Creator

- name: Go Kamesui
  role: author
  orcid: https://orcid.org/0009-0003-1969-5578
- name: Kei Nishikawa
  role: author
  orcid: https://orcid.org/0000-0002-7718-7606
- name: Mikito Ueda
  role: author
  orcid: https://orcid.org/0000-0003-2068-1715
- name: Hisayoshi Matsushima
  role: author
  orcid: https://orcid.org/0000-0001-8612-7640

## Contact agent



## Publisher

organization: The Electrochemical Society

## Managing organization



## Keyword

- subject: morphological variation
  schema: not_defined
- subject: Li electrodeposition
  schema: not_defined
- subject: ionic mass transfer
  schema: not_defined

## Rights

- description: This is the Accepted Manuscript version of an article accepted for
    publication in Journal of The Electrochemical Society. IOP Publishing Ltd is not
    responsible for any errors or omissions in this version of the manuscript or any
    version derived from it.  The Version of Record is available online at https://dx.doi.org/10.1149/1945-7111/ad803d
  identifier: https://creativecommons.org/licenses/by-nc-nd/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-10-08
end_date: 2025-10-08

## Journal

- title: Journal of The Electrochemical Society
  issn: '00134651'
  volume: '171'
  issue: '10'
  article_number: '100507'

## Conference



## Related item



## Funding

- identifier: 23KJ0054
  funder_name: Japan Society for the Promotion of Science
- identifier: JPMJPF2016
  funder_name: Japan Science and Technology Agency

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## Fileset

- id: 78ace0a1-c8e5-4323-af83-a35a2204e10d
  filename: JES Revised Manuscript.docx
  content_type: application/vnd.openxmlformats-officedocument.wordprocessingml.document
  size: 2532362
  md5: 1aa32813b678133ac8452988e1c7abc3

## Thumbnail

fileset_id: 78ace0a1-c8e5-4323-af83-a35a2204e10d
filename: JES Revised Manuscript.docx