# Copper‐Free Synthesis of Cationic Glycidyl Triazolyl Polymers

https://mdr.nims.go.jp/datasets/a5711162-3586-4198-a8bb-e810a4c0ad97

## File

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## Id

a5711162-3586-4198-a8bb-e810a4c0ad97

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-01-10T08:03:54.963477Z

## Updated at

2025-01-11T23:30:57.367529Z

## Published at

2025-01-20T03:31:12.569570Z

## Doi



## First published url

https://doi.org/10.1002/marc.202400416

## Date published

2024-07-02

## Recorded date published

2024-12

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Copper‐Free Synthesis of Cationic Glycidyl Triazolyl Polymers
  title_type: original
  lang: en

## Description

- description: Copper-free synthesis of cationic glycidyl triazolyl polymers (GTPs)
    is achieved through a thermal azide-alkyne cycloaddition reaction between glycidyl
    azide polymer and propiolic acid, followed by decarboxylation and quaternization
    of the triazole unit. For synthesizing nonfunctionalized GTP (GTP-H), a microwave-assisted
    method enhances the decarboxylation reaction of carboxy-functionalized GTP (GTP-COOH).
    Three variants of cationic GTPs with different N-substituents [N-ethyl, N-butyl,
    and N-tri(ethylene glycol) monomethyl ether (EG3)] are synthesized. The molecular
    weight of GTP-H is determined via size exclusion chromatography. Thermal properties
    of all GTPs are characterized using differential scanning calorimetry and thermogravimetric
    analysis. The ionic conductivities of these cationic GTPs are assessed by impedance
    measurements. The conducting ion concentration and mobility are calculated based
    on the electrode polarization model. Among three cationic GTPs, the GTP with the
    N-EG3 substituent exhibits the highest ionic conductivity, reaching 6.8 × 10−6
    Scm−1 at 25 °C under dry conditions.
  description_type: abstract
  lang: und

## Creator

- name: Taichi Ikeda
  role: author
  orcid: https://orcid.org/0000-0001-6650-5798

## Contact agent



## Publisher

organization: Wiley

## Managing organization



## Keyword

- subject: Polymer materials
  schema: not_defined
- subject: Click chemistry
  schema: not_defined
- subject: Ion conductive materials
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Macromolecular Rapid Communications
  issn: '10221336'
  volume: '45'
  issue: '24'

## Conference



## Related item



## Funding

- identifier: Grant‐in‐Aids for Scientific Research C
  funder_name: Japan Society for the Promotion of Science
- identifier: 22K05246
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



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## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



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## Fileset

- id: c2e26f80-9ecf-43c6-a969-07325d9223f9
  filename: 2024-MacroRapid.pdf
  content_type: application/pdf
  size: 941536
  md5: 8e3368f45e4220697cb7029d2823d0da

## Thumbnail

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filename: 2024-MacroRapid.pdf