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説明:

Contaminations in the formation of two-dimensional heterostructures can hinder or generate desired properties. Recent advancements have highlighted the potential of tipenhanced Raman spectroscopy (TERS) for studying materials in the 2D semiconductor class. In this work, we investigate the influence of 50-200nm sized nanoprotuberances within a monolayer of MoSe2 deposited on hBN using nano-Raman spectroscopy, establishing correlations between the presence of localized contaminations and the observed hyperspectral variations. A figure of merit is established for the identification of surface contaminations, based on MoSe2 peaks ratio. Notably, new spectral peaks were identified, which are associated with the presence of nanoprotuberances and may indicate contamination, oxidation, or trapped gases within them.

権利情報:

• Creative Commons BY Attribution 4.0 International
  

キーワード: Nano-Raman Spectroscopy MoSe2

刊行年月日: 2025-10-14

出版者: American Chemical Society (ACS)

掲載誌:

• ACS Nano (ISSN: 1936086X) vol. 19 issue. 40 p. 35438-35446

研究助成金:

• Fundação de Amparo à Pesquisa do Estado de Minas Gerais APQ - 01860-22
• Fundação de Amparo à Pesquisa do Estado de Minas Gerais APQ - 04852-23
• Fundação de Amparo à Pesquisa do Estado de Minas Gerais APQ-01402-23
• Fundação de Amparo à Pesquisa do Estado de Minas Gerais RED - 00081-23
• Fundação de Amparo à Pesquisa do Estado de Minas Gerais RED-00079-23
• Core Research for Evolutional Science and Technology JPMJCR24A5
• Japan Society for the Promotion of Science JP21H05232
• Japan Society for the Promotion of Science JP21H05233
• Japan Society for the Promotion of Science JP21H05234
• Japan Society for the Promotion of Science JP22H00283
• Japan Society for the Promotion of Science JP22H04957
• Japan Society for the Promotion of Science JP23H02052
• Fusion Oriented REsearch for disruptive Science and Technology JPMJFR213X
• Ministry of Education (MOE), Taiwan

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1021/acsnano.5c08036

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更新時刻: 2025-12-09 16:30:45 +0900

MDRでの公開時刻: 2025-12-09 16:26:06 +0900