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Iron-catalyzed graphitization of biomass is a simple and sustainable route to carbons with high graphitic content. In this paper, we demonstrate that the choice of catalyst is also critical to the carbon structure. Aqueous iron(III) nitrate and iron(III) chloride convert cellulose to carbons with very different textural properties. This is due to the choice of iron catalyst changing the mechanism of cellulose decomposition and also the nature of the active graphitization catalyst.

権利情報:

• Creative Commons BY-NC Attribution-NonCommercial 4.0 International
  

キーワード: iron-catalysed graphitization, cellulose

刊行年月日: 2024-10-14

出版者: Royal Society of Chemistry (RSC)

掲載誌:

• RSC Sustainability (ISSN: 27538125) vol. 2 issue. 11 p. 3490-3499

研究助成金:

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1039/D4SU00365A

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更新時刻: 2024-12-10 16:55:16 +0900

MDRでの公開時刻: 2024-12-10 16:55:16 +0900