# Tethering Organic Disulfides to Layered Silicates: A Versatile Strategy for Photo-Controllable Dynamic Chemistry and Functionalization

https://mdr.nims.go.jp/datasets/8d4df259-baab-4e1f-b47e-a589909f0572

## Files

- [Tethering Organic Disulfides_proof.pdf](https://mdr.nims.go.jp/filesets/60307c2a-0306-461c-8afa-c857399b86f3/download) ([Detail](https://mdr.nims.go.jp/filesets/60307c2a-0306-461c-8afa-c857399b86f3.md))
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## Id

8d4df259-baab-4e1f-b47e-a589909f0572

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2023-11-17T05:29:08.366725Z

## Updated at

2024-01-05T13:12:44.811039Z

## Published at

2023-12-12T04:30:27.182140Z

## Doi

https://doi.org/10.48505/nims.4302

## First published url

https://doi.org/10.1246/bcsj.20220309

## Date published

2023-01-15

## Recorded date published

2023-1-15

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: 'Tethering Organic Disulfides to Layered Silicates: A Versatile Strategy
    for Photo-Controllable Dynamic Chemistry and Functionalization'
  title_type: original
  lang: en

## Description

- description: The dynamic covalent chemistry of molecular disulfides has been studied
    extensively in solution, but their reactivity when confined to nanospaces has
    not been investigated, nor has their application to functional nanomaterials been
    explored. In this study, symmetrical organic disulfides were tethered to the basal
    planes of synthetic mica by intercalation, confining photo-induced reactions to
    the interlayer as a result. This approach functionalizes the nanosheets to act
    as host for photo-induced disulfide-disulfide, disulfide-thiol, and disulfide-ene
    reactions, providing control and versatility for a wide variety of applications.
  description_type: abstract
  lang: en

## Creator

- name: Jonathon Tanks
  role: author
  orcid: https://orcid.org/0000-0002-0232-8240
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26
- name: Takashi Hiroi
  role: author
  orcid: https://orcid.org/0000-0001-6881-1334
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26
- name: Kenji Tamura
  role: author
  orcid: https://orcid.org/0000-0001-6578-0923
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26
- name: Kimiyoshi Naito
  role: author
  orcid: https://orcid.org/0000-0002-3334-4876
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26

## Contact agent



## Publisher

organization: The Chemical Society of Japan

## Managing organization



## Keyword

- subject: Disulfide chemistry
  schema: not_defined
- subject: Layered silicates
  schema: not_defined
- subject: Photo-reactivity
  schema: not_defined

## Rights

- description: "©2022 The Chemical Society of Japan"
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Bulletin of the Chemical Society of Japan
  issn: '13480634'
  volume: '96'
  issue: '1'
  start_page: 65
  end_page: 71

## Conference



## Related item



## Funding

- identifier: Grant-in-Aid for Young Scientists (KAKENHI)
  funder_name: JSPS
  description: Understanding the Relationship between Polymer Structure and Creep
    Deformation/Failure by Multiscale Analysis
- identifier: Grant-in-Aid for Scientific Research (KAKENHI)
  funder_name: JSPS
  description: ヒドロキシアルミニウム変質粘土表面における原子・分子レベルのセシウム吸着挙動解析

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



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## Custom property



## Fileset

- id: 60307c2a-0306-461c-8afa-c857399b86f3
  filename: Tethering Organic Disulfides_proof.pdf
  content_type: application/pdf
  size: 459392
  md5: '09cf3c74bcb2562d05fceb8bc27d45db'
- id: 931ff84d-ed16-46a3-9de9-bd7757481a09
  filename: Tethering Organic Disulfides_ESI.pdf
  content_type: application/pdf
  size: 4726179
  md5: 464d49343134758eea3caac4ee1bd9c8

## Thumbnail

fileset_id: 931ff84d-ed16-46a3-9de9-bd7757481a09
filename: Tethering Organic Disulfides_ESI.pdf