# Nanoarchitectonics of Metal–Organic Framework on Fullerene Assemblies: Fabrication of Hierarchical Nanostructured Carbon Electrocatalysts

https://mdr.nims.go.jp/datasets/8c938a62-bef1-4c24-bd9f-0b68a2093025

## File

- [ACS-AMI26_18_28717.pdf](https://mdr.nims.go.jp/filesets/67af97f2-77b6-4787-80c2-824ae2125bb6/download) ([Detail](https://mdr.nims.go.jp/filesets/67af97f2-77b6-4787-80c2-824ae2125bb6.md))

## Id

8c938a62-bef1-4c24-bd9f-0b68a2093025

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2026-05-29T00:05:49.934075Z

## Updated at

2026-05-29T00:44:42.778123Z

## Published at

2026-05-29T03:57:04.908817Z

## Doi



## First published url

https://doi.org/10.1021/acsami.6c03512

## Date published

2026-05-27

## Recorded date published

2026-5-27

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: 'Nanoarchitectonics of Metal–Organic Framework on Fullerene Assemblies: Fabrication
    of Hierarchical Nanostructured Carbon Electrocatalysts'
  title_type: original
  lang: en

## Description

- description: We introduce a comprehensive nanoarchitectonics approach for constructing
    metal–organic framework on fullerene (MOFOF) hybrids with diverse dimensionalities
    spanning 0D nanospheres, 1D nanorods and nanotubes, 2D sheets, and 3D cubic assemblies,
    and demonstrate their potential for electrocatalyst development through the pyrolysis
    of a selected hybrid. Through a sequential layer-by-layer (or, step-by-step) growth
    of a typical MOF (ZIF-67) on self-assembled fullerene supports, we generated a
    family of MOFOF nanostructures with diverse morphologies. Subsequent high-temperature
    carbonization and ammonia-assisted nitrogen doping are expected to transform these
    MOFOF precursors into hierarchical nitrogen-doped Co/C electrocatalysts featuring
    well-defined Co–Nx active sites embedded within graphitized carbon frameworks.
    The superior performance arises from the synergistic integration of Co-supported
    active sites and protective graphitic carbon shells.
  description_type: abstract
  lang: und

## Creator

- name: Rabindra Nath Acharyya
  role: author
  orcid: https://orcid.org/0000-0002-5439-8937
- name: Biswa Nath Bhadra
  role: author
  orcid: https://orcid.org/0000-0001-7268-2563
- name: Sabina Shahi
  role: author
  orcid: https://orcid.org/0000-0002-9198-2470
- name: Kenji Hayashida
  role: author
- name: Shusaku Fujita
  role: author
- name: Kotaro Takeyasu
  role: author
  orcid: https://orcid.org/0000-0002-4472-6992
- name: Katsuhiko Ariga
  role: author
  orcid: https://orcid.org/0000-0002-2445-2955
- name: Lok Kumar Shrestha
  role: author
  orcid: https://orcid.org/0000-0003-2680-6291

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: MOF
  schema: not_defined
- subject: fullerene
  schema: not_defined
- subject: layer-by-layer
  schema: not_defined
- subject: hierarchical nanostructure
  schema: not_defined
- subject: acidic ORR
  schema: not_defined
- subject: durability
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: ACS Applied Materials & Interfaces
  issn: '19448244'
  volume: '18'
  issue: '20'
  start_page: 28717
  end_page: 28727

## Conference



## Related item



## Funding

- identifier: JP23H05459
  funder_name: Japan Society for the Promotion of Science
- identifier: JP25H00898
  funder_name: Japan Society for the Promotion of Science

## Instrument



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## Measurement method



## Specimen



## Chemical composition



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## Structural feature for specimen



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## Fileset

- id: 67af97f2-77b6-4787-80c2-824ae2125bb6
  filename: ACS-AMI26_18_28717.pdf
  content_type: application/pdf
  size: 10957352
  md5: 96ca96cc0e9c4c45a6d8bb3e4cb514c2

## Thumbnail

fileset_id: 67af97f2-77b6-4787-80c2-824ae2125bb6
filename: ACS-AMI26_18_28717.pdf