# Systematic design and functionalisation of amorphous zirconium metal–organic frameworks

https://mdr.nims.go.jp/datasets/87698838-0dd0-4a7c-a39a-a35e95d66c61

## File

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## Id

87698838-0dd0-4a7c-a39a-a35e95d66c61

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-11-08T07:49:59.226519Z

## Updated at

2024-11-11T07:30:18.659492Z

## Published at

2024-11-11T07:30:18.963802Z

## Doi



## First published url

https://doi.org/10.1039/d4sc05053c

## Date published

2024-10-07

## Recorded date published

2024-10-30

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Systematic design and functionalisation of amorphous zirconium metal–organic
    frameworks
  title_type: original
  lang: en

## Description

- description: Controlling the structure and functionality of crystalline metal–organic
    frameworks (MOFs) using molecular building units and post-synthetic functionalisation
    presents challenges when extending this approach to their amorphous counterparts
    (aMOFs). Here, we present a new bottom-up approach for synthesising a series of
    Zr-based aMOFs, which involves linking metal–organic clusters with specific ligands
    to regulate local connectivity. In addition, we overcome the limitations of post-synthetic
    modifications in amorphous systems, demonstrating that homogeneous functionalisation
    is achievable even without regular internal voids. By altering the acidity of
    the side group, length, and degree of connectivity of the linker, we could control
    the porosity, proton conductivity, and mechanical properties of the resulting
    aMOFs.
  description_type: abstract
  lang: und

## Creator

- name: Nattapol Ma
  role: author
  orcid: https://orcid.org/0000-0002-6162-1834
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26
- name: Soracha Kosasang
  role: author
  orcid: https://orcid.org/0009-0006-5254-2890
- name: Jennifer Theissen
  role: author
  orcid: https://orcid.org/0000-0001-7374-8819
- name: Nick Gys
  role: author
  orcid: https://orcid.org/0000-0003-1464-6331
- name: Tom Hauffman
  role: author
- name: Ken-ichi Otake
  role: author
  orcid: https://orcid.org/0000-0002-7904-5003
- name: Satoshi Horike
  role: author
  orcid: https://orcid.org/0000-0001-8530-6364
- name: Rob Ameloot
  role: author
  orcid: https://orcid.org/0000-0003-3178-5480

## Contact agent



## Publisher

organization: Royal Society of Chemistry (RSC)

## Managing organization



## Keyword

- subject: metal-organic frameworks
  schema: not_defined
- subject: amorphous
  schema: not_defined
- subject: bottom-up assembly
  schema: not_defined
- subject: sol-gel synthesis
  schema: not_defined
- subject: functionalisation
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by-nc/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Chemical Science
  issn: '20416520'
  volume: '15'
  issue: '42'
  start_page: 17562
  end_page: 17570

## Conference



## Related item



## Funding



## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



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