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A porous two-dimensional metal–organic network (2D-MON) on a substrate captures deposited metal atoms and metal clusters growing in the pores of the 2D-MON. We found that the growth mechanisms of Ag, In, and Pd clusters in the 2D-MON synthesized from 1,3,5-tris(4-bromophenyl) benzene molecules on Ag(111) are different from each other, and the difference derives from the interaction of an adatom with the 2D-MON. Ag and Pd clusters grow from the 2D-MON since the interaction of Ag and Pd adatoms with the 2D-MON is attractive. In clusters grow inside of the pores of the 2D-MON since the interaction between an In adatom and the 2D-MON is repulsive. The growth process of metal clusters is determined by the element-specific behavior of metal adatoms in the pores, taking into account interactions with the 2D-MON.

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• In Copyright
  This is the version of the article before peer review or editing, as submitted by an author to Japanese Journal of Applied Physics.  IOP Publishing Ltd is not responsible for any errors or omissions in this version of the manuscript or any version derived from it.  The Version of Record is available online at https://doi.org/10.35848/1347-4065/ad50b3

Keyword: two-dimensional metal–organic network

Date published: 2024-06-03

Publisher: IOP Publishing

Journal:

• Japanese Journal of Applied Physics (ISSN: 13474065) vol. 63 issue. 6 065504

Funding:

Manuscript type: Author's original (Submitted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4658

First published URL: https://doi.org/10.35848/1347-4065/ad50b3

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Updated at: 2024-08-20 08:30:34 +0900

Published on MDR: 2024-08-20 08:30:34 +0900