# Iodonium-based pro-adhesive layers for robust adhesion of PEDOT:PSS to surfaces

https://mdr.nims.go.jp/datasets/84424754-de59-436b-8ed6-a3e047cca67e

## File

- [Iodonium-based pro-adhesive layers for robust adhesion of PEDOT PSS to surfaces.pdf](https://mdr.nims.go.jp/filesets/b9da2db0-1f9b-474a-9e24-1b8b18b4add2/download) ([Detail](https://mdr.nims.go.jp/filesets/b9da2db0-1f9b-474a-9e24-1b8b18b4add2.md))

## Id

84424754-de59-436b-8ed6-a3e047cca67e

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-05-02T01:45:30.138737Z

## Updated at

2024-05-08T07:30:36.082208Z

## Published at

2024-05-08T07:30:36.195125Z

## Doi

https://doi.org/10.48505/nims.4501

## First published url

https://doi.org/10.1080/14686996.2024.2338786

## Date published

2024-12-31

## Recorded date published

2024-12-31

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Iodonium-based pro-adhesive layers for robust adhesion of PEDOT:PSS to surfaces
  title_type: original
  lang: en

## Description

- description: Electrochemical grafting of organic molecules to metal surfaces has
    been well-known as an efficient tool enabling tailored modification of surface
    at the nanoscale. Among many compounds with the ability to undergo the process
    of electrografting, iodonium salts belong to less frequently used, especially
    when compared with the most popular diazonium salts. Meanwhile, due to their increased
    stability, iodonium salts may be used in situations where the use of diazonium
    salts is constrained. The aim of this study was to examine the effect of the electrochemical
    reduction of iodonium salts on the physicochemical properties of Pt electrodes,
    and the possibility to form pro-adhesive layers facilitating further functionalization
    purposes. Consequently, we have selected four commercially available iodonium
    salts (diphenyliodonium chloride, bis(4-tertbutylphenyl)iodonium hexafluorophosphate,
    (4-nitrophenyl)(2,4,6-trimethylphenyl)iodonium triflate, bis(4-methylphenyl)iodonium
    hexafluorophosphate), and attached them to the surface of Pt electrodes by means
    of an electrochemical reduction process. As-formed layers were then extensively
    characterized in terms of wettability, roughness and charge transfer properties,
    and used as pro-adhesive coatings prior to the deposition of poly(3,4-ethylenedioxythiophene):poly(styrene
    sulfonate), PEDOT:PSS. Due to the increase in hydrophilicity and roughness, modified
    electrodes increased the stability of PEDOT:PSS coating while maintaining its
    high capacitance.
  description_type: abstract
  lang: en

## Creator

- name: Szymon Smołka
  role: author
  organization: Tottori University
  department: Graduate School of Engineering
- name: Taral Patel
  role: author
- name: Sandra Pluczyk-Małek
  role: author
  organization: Malaysia–Japan International Institute of Technology
- name: Roman Turczyn
  role: author
- name: Katarzyna Krukiewicz
  role: author
  organization: Silesian University of Technology
  department: Department of Physical Chemistry and Technology of Polymers

## Contact agent



## Publisher

organization: Taylor & Francis

## Managing organization



## Keyword

- subject: Adhesion
  schema: not_defined
- subject: charge storage capacity
  schema: not_defined
- subject: charge transfer
  schema: not_defined
- subject: electrografting
  schema: not_defined
- subject: iodonium salts
  schema: not_defined
- subject: PEDOT:PSS
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Science and Technology of Advanced Materials
  issn: '14686996'
  volume: '25'
  issue: '1'
  article_number: '2338786'

## Conference



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## Instrument



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## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



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## Fileset

- id: b9da2db0-1f9b-474a-9e24-1b8b18b4add2
  filename: Iodonium-based pro-adhesive layers for robust adhesion of PEDOT PSS to
    surfaces.pdf
  content_type: application/pdf
  size: 2880455
  md5: 67d0b9f8d3f8785b0ce6372d017a8647

## Thumbnail

fileset_id: b9da2db0-1f9b-474a-9e24-1b8b18b4add2
filename: Iodonium-based pro-adhesive layers for robust adhesion of PEDOT PSS to surfaces.pdf