# Light-Induced Dynamic Restructuring of Cu Active Sites on TiO<sub>2</sub> for Low-Temperature H<sub>2</sub> Production from Methanol and Water

https://mdr.nims.go.jp/datasets/76cda67d-feb6-43c8-8ced-8d18610771e4

## File

- [Light-induced Dynamic Restructuring of Cu Active Sites on TiO2 for Low-temperature H2 Production from Methanol and Water.pdf](https://mdr.nims.go.jp/filesets/eca97dee-b71b-44bd-9070-8d9c5619073e/download) ([Detail](https://mdr.nims.go.jp/filesets/eca97dee-b71b-44bd-9070-8d9c5619073e.md))

## Id

76cda67d-feb6-43c8-8ced-8d18610771e4

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-09-27T07:31:32.330041Z

## Updated at

2024-09-30T07:30:35.233573Z

## Published at

2024-09-30T07:30:35.302526Z

## Doi

https://doi.org/10.48505/nims.4784

## First published url

https://doi.org/10.1021/jacs.3c06688

## Date published

2023-09-20

## Recorded date published

2023-9-20

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Light-Induced Dynamic Restructuring of Cu Active Sites on TiO<sub>2</sub>
    for Low-Temperature H<sub>2</sub> Production from Methanol and Water
  title_type: original
  lang: en

## Description

- description: メタノールからCu/TiO2触媒を利用して、水素を生成させる反応を行った。低温で反応を実施すると、銅が酸化されて、すぐに失活するが、光を照射しながら、反応を実施すると、銅の酸化を抑制でき、活性をキープすることができることが明らかとなった。
  description_type: abstract
  lang: en

## Creator

- name: Shunqin Luo
  role: author
  orcid: https://orcid.org/0000-0002-1162-0200
  organization: National Institute for Materials Science
- name: Hui Song
  role: author
  organization: National Institute for Materials Science
- name: Fumihiko Ichihara
  role: author
  orcid: https://orcid.org/0000-0002-0274-1342
  organization: National Institute for Materials Science
- name: Mitsutake Oshikiri
  role: author
  orcid: https://orcid.org/0000-0002-1856-204X
  organization: National Institute for Materials Science
- name: Wenning Lu
  role: author
- name: Dai-Ming Tang
  role: author
  orcid: https://orcid.org/0000-0001-7136-7481
  organization: National Institute for Materials Science
- name: Sijie Li
  role: author
- name: Yunxiang Li
  role: author
- name: Yifan Li
  role: author
  orcid: https://orcid.org/0000-0001-7997-1456
  organization: National Institute for Materials Science
- name: Philo Davin
  role: author
  orcid: https://orcid.org/0000-0002-1399-7028
  organization: National Institute for Materials Science
- name: Tetsuya Kako
  role: author
  orcid: https://orcid.org/0000-0002-1891-6346
  organization: National Institute for Materials Science
- name: Huiwen Lin
  role: author
  orcid: https://orcid.org/0000-0001-7988-1194
  organization: National Institute for Materials Science
- name: Jinhua Ye
  role: author
  orcid: https://orcid.org/0000-0002-8105-8903
  organization: National Institute for Materials Science

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: hydrogen
  schema: not_defined
- subject: methanol
  schema: not_defined
- subject: Cu
  schema: not_defined
- subject: photothermal
  schema: not_defined

## Rights

- description: This document is the Accepted Manuscript version of a Published Work
    that appeared in final form in Journal of the American Chemical Society, copyright
    © 2023 American Chemical Society after peer review and technical editing by the
    publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.3c06688
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2023-09-07
end_date: 2024-09-07

## Journal

- title: Journal of the American Chemical Society
  issn: '15205126'
  volume: '145'
  issue: '37'
  start_page: 20530
  end_page: 20538

## Conference



## Related item



## Funding

- funder_name: Hokkaido University
- identifier: JP18H02065
  funder_name: Japan Society for the Promotion of Science
- identifier: JP21K04782
  funder_name: Japan Society for the Promotion of Science
- identifier: '42103016'
  funder_name: National Natural Science Foundation of China
- funder_name: World Premier International Research Center Initiative

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: eca97dee-b71b-44bd-9070-8d9c5619073e
  filename: Light-induced Dynamic Restructuring of Cu Active Sites on TiO2 for Low-temperature
    H2 Production from Methanol and Water.pdf
  content_type: application/pdf
  size: 1223260
  md5: 966161e03f2b087f4c59d6816f006acd

## Thumbnail

fileset_id: eca97dee-b71b-44bd-9070-8d9c5619073e
filename: Light-induced Dynamic Restructuring of Cu Active Sites on TiO2 for Low-temperature
  H2 Production from Methanol and Water.pdf