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To promote sustainable development and reduce fossil fuel consumption, there is a growing demand for high-performance, cost-effective, safe and environmentally friendly batteries for large-scale energy storage systems. Among the emerging technologies, zinc-air batteries (ZABs) have attracted significant interest. By integrating the principles of traditional zinc-ion batteries and fuel cells, ZABs offer remarkably high theoretical energy density at lower production cost compared to the current state-of-the-art lithium-ion batteries (LIBs). However, the critical challenge remains in developing high-performance zinc anode. Herein, this review provides a comprehensive analysis of the current status and advancements in zinc anodes for rechargeable aqueous ZABs. We begin by highlighting the major challenges and underlying mechanisms associated with zinc anodes including issues such as uneven zinc deposition, dendrite growth and hydrogen evolution reaction. Then, this review discusses the recent advancements in zinc anode modifications, focusing on strategies such as alloying, surface porosity and zincophilicity. By reviewing the latest research, we also identify existing gaps and pose critical questions that need further exploration to push the field forward. The goal of this review is to inspire new research directions and promote the development of more efficient zinc anodes.

権利情報:

• Creative Commons BY Attribution 4.0 International
  

キーワード: zinc-air batteries, zinc anode, dendrite-free, surface modification, structural design, cycle stability

刊行年月日: 2025-12-31

出版者: Taylor & Francis

掲載誌:

• Science and Technology of Advanced Materials (ISSN: 14686996) vol. 26 2448418

研究助成金:

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5312

公開URL: https://doi.org/10.1080/14686996.2024.2448418

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更新時刻: 2025-07-16 16:17:06 +0900

MDRでの公開時刻: 2025-02-07 12:30:18 +0900