# Heterometallic supramolecular polymers: From synthesis to properties and applications

https://mdr.nims.go.jp/datasets/6f720fdc-a4b9-4b6a-83fc-ffacbb4f95ea

## File

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## Id

6f720fdc-a4b9-4b6a-83fc-ffacbb4f95ea

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-11-27T05:51:27.998549Z

## Updated at

2024-11-29T07:32:08.582776Z

## Published at

2024-11-29T07:32:08.671229Z

## Doi

https://doi.org/10.48505/nims.5059

## First published url

https://doi.org/10.1016/j.ccr.2023.215573

## Date published

2023-12-12

## Recorded date published

2024-2

## Resource type

journal_article

## Manuscript type

authors_original

## Collection



## Title

- title: 'Heterometallic supramolecular polymers: From synthesis to properties and
    applications'
  title_type: original
  lang: en

## Description

- description: Heterometallic supramolecular polymers (HMSPs) comprising two or more
    heterometal ions have drawn significant research interest in the last two decades
    because of their attractive properties and applications owing to the combination
    of organic and inorganic segments in the polymer as well as that of heterometallic
    complexes in the polymer chain. However, the synthesis of HMSPs is challenging
    because of the different stabilities of heterometallic complexes. To date, various
    HMSPs have been developed via one-pot or stepwise synthetic approaches, in which
    heterometal ions are complexed in identical or different coordination environments.
    The properties of this type of polymers not only depend on the heterometal ions,
    but also on the coordination environments of heterometal ions. In this review,
    we summarize the progress made in the synthesis of HMSPs and highlight their properties
    and applications. In the first section, we comprehensively discuss various synthetic
    approaches to HMSPs with all relevant reported examples. Subsequently, we highlight
    the properties and applications explored in different research directions. Finally,
    we provide a perspective on the synthetic challenges and future research prospects
    for HMSPs. We believe that this review will provide a roadmap for further developments
    in this thriving area of research to create novel functional materials.
  description_type: abstract
  lang: en

## Creator

- name: Manas Kumar Bera
  role: author
- name: Sanjib Sarmah
  role: author
- name: Dines Chandra Santra
  role: author
  organization: National Institute for Materials Science
- name: Masayoshi Higuchi
  role: author
  orcid: https://orcid.org/0000-0001-9877-1134
  organization: National Institute for Materials Science

## Contact agent



## Publisher

organization: Elsevier BV

## Managing organization



## Keyword

- subject: Heterometallic supramolecular polymer
  schema: not_defined
- subject: One-pot synthesis
  schema: not_defined
- subject: Stepwise synthesis
  schema: not_defined
- subject: Heterometal ions
  schema: not_defined
- subject: Electrochromic application
  schema: not_defined

## Rights

- identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Coordination Chemistry Reviews
  issn: '00108545'
  volume: '501'
  article_number: '215573'

## Conference



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## Instrument



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## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



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## Fileset

- id: 3516baf8-1d4d-4c13-9445-e4bb9a2ce5c1
  filename: Heterometallic supramolecular polymers From synthesis to properties and
    applications.pdf
  content_type: application/pdf
  size: 2726007
  md5: ad221799b34647f489da7c672ba30b82

## Thumbnail

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filename: Heterometallic supramolecular polymers From synthesis to properties and
  applications.pdf