# Droplet Green Chemistry Using Thermally Shape-Reconfigurable Omniphobic Colloidosomes

https://mdr.nims.go.jp/datasets/6d1b62cc-68b5-4060-8ae2-ac83055113aa

## File

- [著者最終稿.pdf](https://mdr.nims.go.jp/filesets/95f76770-8256-45a1-8d2c-3aa08d187334/download) ([Detail](https://mdr.nims.go.jp/filesets/95f76770-8256-45a1-8d2c-3aa08d187334.md))

## Id

6d1b62cc-68b5-4060-8ae2-ac83055113aa

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-09-26T02:20:14.410965Z

## Updated at

2025-06-20T23:30:18.208505Z

## Published at

2025-06-20T23:19:23.380444Z

## Doi

https://doi.org/10.48505/nims.4774

## First published url

https://doi.org/10.1021/acs.chemmater.4c01261

## Date published

2024-06-21

## Recorded date published



## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Droplet Green Chemistry Using Thermally Shape-Reconfigurable Omniphobic Colloidosomes
  title_type: original
  lang: en

## Description

- description: A high-yield, lossless chemical reaction conducted under ambient conditions
    is promising in Green Chemistry. However, owing to the sticky feature of liquids
    on solid surfaces and the high volatility of useful primary solvents, "droplet
    chemistry" is far from practical use. Thus, a droplet platform that prevents both
    the droplet's evaporation and adhesion losses is promising. Herein, we report
    a versatile method for droplet encapsulation with poly octadecyl acrylate (PODAc)
    based on the colloidosome technique. The PODAc colloidosomes are mechanochemically
    stable and thermally shape-reconfigurable while maintaining their surface omniphobicity.
    This feature enabled PODAc colloidosomes to load typical liquids regardless of
    their surface tension without experiencing evaporation or adhesion loss, transport
    like solid beads, and release inner liquid on-demand by heating or NIR light irradiation.
    The colloidosome is mass-producible and recyclable by a simple thermomechanical
    process. As a proof-of-concept, different droplet-scale reactions are demonstrated
    in colloidosomes using volatile microliter solvent and volatile reactants.
  description_type: abstract
  lang: und

## Creator

- name: Karan Jain
  role: author
- name: Saurav Kumar
  role: author
- name: Manideepa Dhar
  role: author
- name: Haydar Ali
  role: author
- name: Nishanta Barman
  role: author
- name: Debasmita Sarkar
  role: author
- name: Mizuki Tenjimbayashi
  role: author
  orcid: https://orcid.org/0000-0002-8107-8285
- name: Uttam Manna
  role: author
  orcid: https://orcid.org/0000-0003-3204-158X

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: Droplet green chemistry
  schema: not_defined
- subject: Omniphobic
  schema: not_defined
- subject: Liquid marble
  schema: not_defined
- subject: Colloidosome
  schema: not_defined

## Rights

- description: This document is the unedited Author’s version of a Submitted Work
    that was subsequently accepted for publication in Chemistry of Materials, copyright
    © 2024 American Chemical Society after peer review. To access the final edited
    and published work see https://doi.org/10.1021/acs.chemmater.4c01261
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-06-21
end_date: 2025-06-21

## Journal

- title: Chemistry of Materials
  issn: '08974756'
  volume: '36'
  issue: '18'

## Conference



## Related item



## Funding

- identifier: 5(1)/2022-NANO
  funder_name: Ministry of Electronics and Information technology
- identifier: CRG/2022/000710
  funder_name: Science and Engineering Research Board
- identifier: BT/PR45283/NER/95/1919/2022
  funder_name: Department of Biotechnology, Ministry of Science and Technology, India
- funder_name: Ministry of Education, India
- identifier: SR/FST/CS-II/2017/23C
  funder_name: DST

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## Fileset

- id: 95f76770-8256-45a1-8d2c-3aa08d187334
  filename: 著者最終稿.pdf
  content_type: application/pdf
  size: 1839736
  md5: 0c0ecdcaaff30ad892e5e6d3b9760481

## Thumbnail

fileset_id: 95f76770-8256-45a1-8d2c-3aa08d187334
filename: 著者最終稿.pdf