# Molecular Design of Naphthalene‐ and Carbazole‐Based Monomers for Regiospecific Synthesis of Poly(arylenevinylene)s via Co‐Catalyzed Hydroarylation Polyaddition

https://mdr.nims.go.jp/datasets/67cce730-53f6-4aa3-b66b-e778b5494bbd

## File

- [Iwamori_MARC24_SI.pdf](https://mdr.nims.go.jp/filesets/6a6a9e41-dced-4c33-ba45-02010745aeac/download) ([Detail](https://mdr.nims.go.jp/filesets/6a6a9e41-dced-4c33-ba45-02010745aeac.md))
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## Id

67cce730-53f6-4aa3-b66b-e778b5494bbd

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-08-21T05:03:08.981319Z

## Updated at

2025-04-21T03:30:09.656270Z

## Published at

2025-04-21T03:20:35.648902Z

## Doi

https://doi.org/10.48505/nims.4705

## First published url

https://doi.org/10.1002/marc.202400168

## Date published

2024-04-21

## Recorded date published

2024-8

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Molecular Design of Naphthalene‐ and Carbazole‐Based Monomers for Regiospecific
    Synthesis of Poly(arylenevinylene)s via Co‐Catalyzed Hydroarylation Polyaddition
  title_type: original
  lang: en

## Description

- description: We explored the appropriate monomer structures and reaction conditions
    for the site- and regio-selective hydroarylation polyaddition of PAHs using a
    Co-catalyst. As poly(naphthalene) and poly(naphthalenevinylene) derivatives linked
    at β-positions show high fluorescence quantum yields (Φ > 0.7) and have been applied
    to OLEDs, 2,6-di(1-pyrazolyl)naphthalene was designed as a new naphthalene monomer.
    A site- and regio-selective hydroarylation polyaddition proceeded smoothly under
    mild reaction conditions to obtain the corresponding PAV. In addition, this monomer
    design was applicable to the hydroarylation polyaddition of a carbazole unit.
    Furthermore, the optical and electronic properties of the synthesized PAVs were
    evaluated.
  description_type: abstract
  lang: und

## Creator

- name: Ryota Iwamori
  role: author
- name: Junpei Kuwabara
  role: author
- name: Takeshi Yasuda
  role: author
  orcid: https://orcid.org/0000-0003-4652-9105
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26
- name: Takaki Kanbara
  role: author

## Contact agent



## Publisher

organization: Wiley

## Managing organization



## Keyword

- subject: Hydroarylation Polyaddition
  schema: not_defined
- subject: Poly(arylenevinylene)s
  schema: not_defined
- subject: Regiospecific Synthesis
  schema: not_defined
- subject: Organic light-emitting diode
  schema: not_defined

## Rights

- description: 'This is the peer reviewed version of the following article: R. Iwamori,
    J. Kuwabara, T. Yasuda, T. Kanbara, Molecular Design of Naphthalene- and Carbazole-Based
    Monomers for Regiospecific Synthesis of Poly(arylenevinylene)s via Co-Catalyzed
    Hydroarylation Polyaddition. Macromol. Rapid Commun. 2024, 45, 2400168, which
    has been published in final form at https://doi.org/10.1002/marc.202400168. This
    article may be used for non-commercial purposes in accordance with Wiley Terms
    and Conditions for Use of Self-Archived Versions. This article may not be enhanced,
    enriched or otherwise transformed into a derivative work, without express permission
    from Wiley or by statutory rights under applicable legislation. Copyright notices
    must not be removed, obscured or modified. The article must be linked to Wiley’s
    version of record on Wiley Online Library and any embedding, framing or otherwise
    making available the article or pages thereof by third parties from platforms,
    services and websites other than Wiley Online Library must be prohibited.'
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-04-21
end_date: 2025-04-21

## Journal

- title: Macromolecular Rapid Communications
  issn: '10221336'
  volume: '45'
  issue: '16'
  article_number: '2400168'

## Conference



## Related item



## Funding

- identifier: 23KJ0240
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



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## Fileset

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  filename: Iwamori_MARC24_SI.pdf
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## Thumbnail

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filename: Iwamori_MARC24_SI.pdf