# Mild selective photochemical oxidation of an organic sulfide using OxP-polyimide porous polymers as singlet oxygen generators

https://mdr.nims.go.jp/datasets/62ac71d0-a760-4ead-ada4-d50242a8c06c

## File

- [STAM24_25_2322458.pdf](https://mdr.nims.go.jp/filesets/b95a4b42-d4dc-46be-a179-d4ab5958e46e/download) ([Detail](https://mdr.nims.go.jp/filesets/b95a4b42-d4dc-46be-a179-d4ab5958e46e.md))

## Id

62ac71d0-a760-4ead-ada4-d50242a8c06c

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-03-08T02:52:53.539289Z

## Updated at

2024-03-19T07:56:42.254362Z

## Published at

2024-03-19T07:56:42.383488Z

## Doi



## First published url

https://doi.org/10.1080/14686996.2024.2322458

## Date published

2024-12-31

## Recorded date published

2024-12-31

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Mild selective photochemical oxidation of an organic sulfide using OxP-polyimide
    porous polymers as singlet oxygen generators
  title_type: original
  lang: en

## Description

- description: A series of porous organic polymers based on a singlet oxygen generating
    oxoporphyinogen　(‘OxP’) has been successfully prepared from a pseudotetrahedral
    OxP-tetraamine precursor　(OxP(4-NH2Bn)4) by its reaction with tetracarboxylic
    acid dianhydrides under suitable　conditions. Of the compounds studied, those containing
    naphthalene (OxP-N) and perylene　(OxP-P) spacers, respectively, have large surface
    areas (~530 m2 g-1). On the other hand, the　derivative with a simple benzene spacer
    (OxP-B) exhibits the best 1O2 generating capability.
  description_type: abstract
  lang: und

## Creator

- name: Jan Hynek
  role: author
- name: Daniel T. Payne
  role: author
- name: Lok Kumar Shrestha
  role: author
  orcid: https://orcid.org/0000-0003-2680-6291
- name: Mandeep K. Chahal
  role: author
- name: Renzhi Ma
  role: author
  orcid: https://orcid.org/0000-0001-7126-2006
- name: Jiang Dong
  role: author
- name: Katsuhiko Ariga
  role: author
  orcid: https://orcid.org/0000-0002-2445-2955
- name: Yusuke Yamauchi
  role: author
- name: Jonathan P. Hill
  role: author
  orcid: https://orcid.org/0000-0002-4229-5842

## Contact agent



## Publisher

organization: Informa UK Limited

## Managing organization



## Keyword

- subject: Singlet oxygen generation
  schema: not_defined
- subject: oxoporphyrinogen
  schema: not_defined
- subject: porous polymer
  schema: not_defined
- subject: selective oxidation
  schema: not_defined
- subject: organic sulfide
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by-nc/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Science and Technology of Advanced Materials
  issn: '14686996'
  volume: '25'
  issue: '1'

## Conference



## Related item



## Funding

- identifier: JP20H00392 and JP23H05459
  funder_name: Japan Society for the Promotion of Science
- identifier: JPMJER2003
  funder_name: JST-ERATO

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: b95a4b42-d4dc-46be-a179-d4ab5958e46e
  filename: STAM24_25_2322458.pdf
  content_type: application/pdf
  size: 11824106
  md5: e56c2c7edcd535c05502be1d7e7b88d8

## Thumbnail

fileset_id: b95a4b42-d4dc-46be-a179-d4ab5958e46e
filename: STAM24_25_2322458.pdf