Jan Hynek
;
Daniel T. Payne
;
Lok Kumar Shrestha
;
Mandeep K. Chahal
;
Renzhi Ma
;
Jiang Dong
;
Katsuhiko Ariga
;
Yusuke Yamauchi
;
Jonathan P. Hill
Collection
Citation
Description:
(abstract)A series of porous organic polymers based on a singlet oxygen generating oxoporphyinogen (‘OxP’) has been successfully prepared from a pseudotetrahedral OxP-tetraamine precursor (OxP(4-NH2Bn)4) by its reaction with tetracarboxylic acid dianhydrides under suitable conditions. Of the compounds studied, those containing naphthalene (OxP-N) and perylene (OxP-P) spacers, respectively, have large surface areas (~530 m2 g-1). On the other hand, the derivative with a simple benzene spacer (OxP-B) exhibits the best 1O2 generating capability.
Rights:
Keyword: Singlet oxygen generation, oxoporphyrinogen, porous polymer, selective oxidation, organic sulfide
Date published: 2024-12-31
Publisher: Informa UK Limited
Journal:
- Science and Technology of Advanced Materials (ISSN: 14686996) vol. 25 issue. 1
Funding:
- Japan Society for the Promotion of Science JP20H00392 and JP23H05459
- JST-ERATO JPMJER2003
Manuscript type: Publisher's version (Version of record)
MDR DOI:
First published URL: https://doi.org/10.1080/14686996.2024.2322458
Related item:
Other identifier(s):
Contact agent:
Updated at: 2024-03-19 16:56:42 +0900
Published on MDR: 2024-03-19 16:56:42 +0900
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