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説明:

Pseudorotaxanes, which are formed by macrocyclic host molecules and linear guest molecules, show potential in molecular devices and surface applications. In this study, ethoxy-functionalized pillar[5]arene (P5A) and amphiphilic linear fatty acid guests were self-assembled into oriented monolayers at the air–water interface. The fatty acid structure dictates the monolayer formation: [2]pseudorotaxane-based, [3]pseudorotaxane-based and phase-separated monolayers. These findings provide insights into P5A-based pseudorotaxane monolayers, facilitating their integration into advanced functional materials.

権利情報:

• cc-by-nc-3.0
  

キーワード: Pseudorotaxane, monolayer, air–water interface, pillar[5]arene, fatty acid

刊行年月日: 2025-06-05

出版者: Royal Society of Chemistry (RSC)

掲載誌:

• Chemical Communications (ISSN: 13597345) vol. 61 issue. 55 p. 10138-10141

研究助成金:

• Japan Science and Technology Corporation JPMJFS2144
• Japan Science and Technology Corporation JP25H00898
• Japan Science and Technology Corporation JP23H05459
• Japan Science and Technology Corporation JP23K04703

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1039/d5cc01040c

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更新時刻: 2025-07-07 12:30:21 +0900

MDRでの公開時刻: 2025-07-07 12:20:59 +0900