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説明:

The arrangement of ions at the interface between highly oriented pyrolytic graphite (HOPG) and Aluminum chloride–1-ehtyl-3methylimidazolium chloride (AlCl3–EmImCl) ionic liquid was evaluated using Atomic Force Microscopy (AFM) force curve measurements. In the force curve measurements, three steps were observed towards the HOPG electrode. The width of each step was 0.3, 0.4, and 0.5nm in order from the final arrival point. Their step widths were regarded as the thicknesses of EmIm+, Al2Cl7−, or their mixed layers. The force curve measurements at each potential demonstrated that the width of the first layer close to the HOPG tended to decrease as the potential shifted towards the less noble side.

権利情報:

• Creative Commons BY Attribution 4.0 International
  

キーワード: Ionic Liquid, AFM

刊行年月日: 2024-04-01

出版者: The Electrochemical Society of Japan

掲載誌:

• Electrochemistry (ISSN: 13443542) vol. 92 issue. 4 p. 43011- 23-69151

研究助成金:

• Japan Society for the Promotion of Science 21K04734

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.5796/electrochemistry.23-69151

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更新時刻: 2024-10-13 08:30:29 +0900

MDRでの公開時刻: 2024-10-13 08:30:29 +0900