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説明:

Advances have focused on disulfide-based epoxy-covalent adaptable network (CAN) polymer systems, which leverage reversible disulfide exchange reactions. The evolution from conventional carbon fiber reinforced thermosetting composites (CFRPs) to disulfide-based epoxy-CAN polymer composites represents a paradigm shift toward sustainable, high-performance materials. Recently, Teijin Ltd. has developed disulfide-based epoxy-CAN CFRP (carbon fiber: IMS65; resin: DGEBA/4-APD/PES5003P (disulfide-based epoxy-CAN polymer)). In this study, the mode-I and mode-II interlaminar fracture properties of the disulfide-based epoxy-CAN CFRP were investigated. The mode-I and mode-II interlaminar fracture tests were conducted under static loading using a double cantilever beam and end notched flexure specimens. The values of the mode-I and mode-II interlaminar fracture toughness of the disulfide-based epoxy-CAN CFRP were 0.293 and 1.054 kN/m, which were higher than those of conventional epoxy CFRP. The fracture surfaces of the disulfide-based epoxy-CAN CFRP were rougher than those of conventional epoxy CFRP. These improvements are attributed to enhanced fiber bridging, plastic deformation, and the dynamic disulfide exchange mechanism, which promote energy dissipation and interfacial adhesion. Compared to conventional epoxy CFRPs, the novel composite exhibits superior delamination resistance, recyclability, and potential for self-healing.

権利情報:

• Creative Commons BY Attribution 4.0 International
  

キーワード: Carbon fiber reinforced plastics, Epoxy-covalent adaptable network (CAN), Interlaminar fracture property

刊行年月日: 2026-01-29

出版者: Elsevier BV

掲載誌:

• Materials Today Communications (ISSN: 23524928) vol. 51 114737

研究助成金:

• Japan Science and Technology Agency JPMJKP24W1

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1016/j.mtcomm.2026.114737

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更新時刻: 2026-01-31 12:30:21 +0900

MDRでの公開時刻: 2026-01-31 09:36:20 +0900