# Effects of Thiophene-Fused Isomer on High-Layered Crystallinity in π-Extended and Alkylated Organic Semiconductors

https://mdr.nims.go.jp/datasets/4dd9d6a2-4cee-4a63-831a-b2ba7a6e5726

## File

- [Higashino_ChemMater2024_author-fin.pdf](https://mdr.nims.go.jp/filesets/8f5b2e2b-418d-4c30-b562-c18e49358dd0/download) ([Detail](https://mdr.nims.go.jp/filesets/8f5b2e2b-418d-4c30-b562-c18e49358dd0.md))

## Id

4dd9d6a2-4cee-4a63-831a-b2ba7a6e5726

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-08-09T07:12:09.512635Z

## Updated at

2025-01-05T07:30:37.808258Z

## Published at

2025-01-05T07:30:37.930005Z

## Doi

https://doi.org/10.48505/nims.4651

## First published url

https://doi.org/10.1021/acs.chemmater.3c02500

## Date published

2024-01-23

## Recorded date published

2024-1-23

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Effects of Thiophene-Fused Isomer on High-Layered Crystallinity in π-Extended
    and Alkylated Organic Semiconductors
  title_type: original
  lang: en

## Description

- description: 有機半導体の電子機能の源であるπ電子骨格としてこれまでベンゼン骨格やチオフェン骨格やならんだものが用いられている。今回ベンゾチエノベンゾチオフェン（BTBT）にチオフェン環のを付与したBTBTT半導体において、チオフェン環やアルキル鎖の置換位置の異なる異性体を作製して、その異性化が結晶性、成膜性および電界効果トランジスタ特性に及ぼす影響を系統的に調べた。
  description_type: abstract
  lang: und

## Creator

- name: Toshiki Higashino
  role: author
- name: Satoru Inoue
  role: author
- name: Shunto Arai
  role: author
  orcid: https://orcid.org/0000-0002-0055-3006
  organization: National Institute for Materials Science
- name: Seiji Tsuzuki
  role: author
- name: Hiroyuki Matsui
  role: author
- name: Reiji Kumai
  role: author
- name: Kiyofumi Takaba
  role: author
- name: Saori Maki-Yonekura
  role: author
- name: Hirofumi Kurokawa
  role: author
- name: Ichiro Inoue
  role: author
- name: Kensuke Tono
  role: author
- name: Koji Yonekura
  role: author
- name: Tatsuo Hasegawa
  role: author

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: organic semiconductors
  schema: not_defined
- subject: organic transistors
  schema: not_defined
- subject: solution process
  schema: not_defined

## Rights

- description: This document is the Accepted Manuscript version of a Published Work
    that appeared in final form in Chemistry of Materials, copyright © 2024 American
    Chemical Society after peer review and technical editing by the publisher. To
    access the final edited and published work see https://doi.org/10.1021/acs.chemmater.3c02500
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-01-05
end_date: 2025-01-05

## Journal

- title: Chemistry of Materials
  issn: '15205002'
  volume: '36'
  issue: '2'
  start_page: 848
  end_page: 859

## Conference



## Related item



## Funding

- identifier: JPMJMI20G5
  funder_name: JST-Mirai Program
- identifier: JPMJCR18J2
  funder_name: Core Research for Evolutional Science and Technology
- identifier: 18K19161
  funder_name: Japan Society for the Promotion of Science
- identifier: 20H05867
  funder_name: Japan Society for the Promotion of Science
- identifier: 21H04651
  funder_name: Japan Society for the Promotion of Science
- identifier: 21K14699
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 8f5b2e2b-418d-4c30-b562-c18e49358dd0
  filename: Higashino_ChemMater2024_author-fin.pdf
  content_type: application/pdf
  size: 1849439
  md5: 2510af4e9751d3762fcd80445f721e11

## Thumbnail

fileset_id: 8f5b2e2b-418d-4c30-b562-c18e49358dd0
filename: Higashino_ChemMater2024_author-fin.pdf