# Sustaining syngas production at a near-unity H<sub>2</sub>/CO ratio in the photo-induced dry reforming of methane independent of the reactant gas composition

https://mdr.nims.go.jp/datasets/4b364656-63b2-46cf-9ca9-3347430788c1

## File

- [Kaneko_DRM_ChemCom_Manuscript_highlight_2最終版_MDR用.docx](https://mdr.nims.go.jp/filesets/7f2f5996-a603-432d-b36c-2d807fe22ad7/download) ([Detail](https://mdr.nims.go.jp/filesets/7f2f5996-a603-432d-b36c-2d807fe22ad7.md))

## Id

4b364656-63b2-46cf-9ca9-3347430788c1

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-11-28T01:12:16.950881Z

## Updated at

2025-08-21T23:30:19.022535Z

## Published at

2025-08-21T23:17:05.859935Z

## Doi

https://doi.org/10.48505/nims.5171

## First published url

https://doi.org/10.1039/d4cc03088e

## Date published

2024-08-22

## Recorded date published

2024-9-16

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Sustaining syngas production at a near-unity H<sub>2</sub>/CO ratio in the
    photo-induced dry reforming of methane independent of the reactant gas composition
  title_type: original
  lang: en

## Description

- description: A syngas was generated at a near-unity H2/CO ratio independent of the
    reactant gas composition over Rh-loaded strontium titanate in the photo-induced
    dry reforming of methane. Moreover, light irradiation inhibited side reactions,
    such as the reverse water gas shift reaction and the precipitation of the solid-state
    carbon. These results were not explained by thermodynamic equilibrium, but were
    presumably owing to the unique effect of the photogenerated electron–hole pairs.
  description_type: abstract
  lang: und

## Creator

- name: Hiroaki Kaneko
  role: author
  orcid: https://orcid.org/0009-0008-9883-1967
- name: Yohei Cho
  role: author
  orcid: https://orcid.org/0000-0002-6516-2567
- name: Tomotaka Sugimura
  role: author
  orcid: https://orcid.org/0009-0002-7298-9156
- name: Ayako Hashimoto
  role: author
  orcid: https://orcid.org/0000-0002-1985-7667
- name: Akira Yamaguchi
  role: author
  orcid: https://orcid.org/0000-0002-3550-4239
- name: Masahiro Miyauchi
  role: author
  orcid: https://orcid.org/0000-0001-8889-2645

## Contact agent



## Publisher

organization: Royal Society of Chemistry (RSC)

## Managing organization



## Keyword

- subject: Photo-induced catalysis
  schema: not_defined
- subject: Dry reforming of methane
  schema: not_defined

## Rights

- identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-08-22
end_date: 2025-08-22

## Journal

- title: Chemical Communications
  issn: '13597345'
  volume: '60'
  issue: '75'
  start_page: 10406
  end_page: 10409

## Conference



## Related item



## Funding

- identifier: 23H02042
  funder_name: Japan Society for the Promotion of Science
  description: KAKENHI
- identifier: 23K17953
  funder_name: Japan Society for the Promotion of Science
  description: KAKENHI
- identifier: 23K26735
  funder_name: Japan Society for the Promotion of Science
  description: KAKENHI
- identifier: JPJ004596
  funder_name: " Acquisition, Technology & Logistics Agency"
  description: Innovative Science and Technology Initiative for Security

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 7f2f5996-a603-432d-b36c-2d807fe22ad7
  filename: Kaneko_DRM_ChemCom_Manuscript_highlight_2最終版_MDR用.docx
  content_type: application/vnd.openxmlformats-officedocument.wordprocessingml.document
  size: 12181699
  md5: 43b9ab1e1dc38f60c278597d5ecf1e70

## Thumbnail

fileset_id: 7f2f5996-a603-432d-b36c-2d807fe22ad7
filename: Kaneko_DRM_ChemCom_Manuscript_highlight_2最終版_MDR用.docx