# Anomalous Interfacial Electron-Transfer Kinetics in Twisted Trilayer Graphene Caused by Layer-Specific Localization

https://mdr.nims.go.jp/datasets/49e0d9ed-99d9-4fd1-a95b-94cd0e70f97e

## File

- [acscentsci.3c00326.pdf](https://mdr.nims.go.jp/filesets/887af055-0559-4abd-81a5-542a72c2e67d/download) ([Detail](https://mdr.nims.go.jp/filesets/887af055-0559-4abd-81a5-542a72c2e67d.md))

## Id

49e0d9ed-99d9-4fd1-a95b-94cd0e70f97e

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-02-25T01:23:48.202989Z

## Updated at

2025-02-25T23:30:33.030722Z

## Published at

2025-02-25T23:30:33.141083Z

## Doi



## First published url

https://doi.org/10.1021/acscentsci.3c00326

## Date published

2023-06-28

## Recorded date published

2023-6-28

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Anomalous Interfacial Electron-Transfer Kinetics in Twisted Trilayer Graphene
    Caused by Layer-Specific Localization
  title_type: original
  lang: en

## Description

- description: Interfacial electron-transfer (ET) reactions underpin the interconversion
    of electrical and chem- ical energy. Pioneering experiments showed that the ET
    rate depends on the Fermi–Dirac dis- tribution of the electronic density of states
    (DOS) of the electrode, formalized in the Marcus– Hush–Chidsey (MHC) model. Here,
    by controlling interlayer twists in well-defined trilayer graphene moir ́es, we
    show that ET rates are strikingly dependent on electronic localization in each
    atomic layer, and not the overall DOS. The large degree of tunability inherent
    to moir ́e electrodes leads to local ET kinetics that range over three orders
    of magnitude across different constructions of only three atomic layers, even
    exceeding rates at bulk metals. Our results demonstrate that beyond the ensemble
    DOS, electronic localization is critical in facilitating interfacial ET, with
    implications for understanding the origin of high interfacial reactivity typ-
    ically exhibited by defects at electrode–electrolyte interfaces.
  description_type: abstract
  lang: und

## Creator

- name: Kaidi Zhang
  role: author
- name: Yun Yu
  role: author
- name: Stephen Carr
  role: author
- name: Mohammad Babar
  role: author
- name: Ziyan Zhu
  role: author
- name: Bryan Junsuh Kim
  role: author
- name: Catherine Groschner
  role: author
- name: Nikta Khaloo
  role: author
- name: Takashi Taniguchi
  role: author
  orcid: https://orcid.org/0000-0002-1467-3105
  organization: National Institute for Materials Science
- name: Kenji Watanabe
  role: author
  orcid: https://orcid.org/0000-0003-3701-8119
  organization: National Institute for Materials Science
- name: Venkatasubramanian Viswanathan
  role: author
- name: D. Kwabena Bediako
  role: author

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: Interfacial electron-transfer
  schema: not_defined
- subject: trilayer graphene
  schema: not_defined
- subject: electronic localization
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin



## Embargo



## Journal

- title: ACS Central Science
  issn: '23747943'
  volume: '9'
  issue: '6'
  start_page: 1119
  end_page: 1128

## Conference



## Related item



## Funding

- identifier: '10637'
  funder_name: Gordon and Betty Moore Foundation
- identifier: '993922'
  funder_name: W. M. Keck Foundation
- identifier: N00014-18-S-F009
  funder_name: Office of Naval Research
- identifier: N00014-20-1-2599
  funder_name: Office of Naval Research
- identifier: 19H05790
  funder_name: Japan Society for the Promotion of Science
- identifier: 20H00354
  funder_name: Japan Society for the Promotion of Science
- identifier: 21H05233
  funder_name: Japan Society for the Promotion of Science
- identifier: DE-AC02-05CH11231
  funder_name: U.S. Department of Energy
- identifier: DE-SC0021049
  funder_name: U.S. Department of Energy
- identifier: '67507585'
  funder_name: 3M Foundation
- identifier: GS21-011
  funder_name: Canadian Institute for Advanced Research
- identifier: OIA-1921199
  funder_name: National Science Foundation

## Instrument



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## Specimen



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## Fileset

- id: 887af055-0559-4abd-81a5-542a72c2e67d
  filename: acscentsci.3c00326.pdf
  content_type: application/pdf
  size: 5053124
  md5: b86856f9dc78489657409bd37db53877

## Thumbnail

fileset_id: 887af055-0559-4abd-81a5-542a72c2e67d
filename: acscentsci.3c00326.pdf