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Synthesis of an unexplored cardo-typed optical material showing a high refractive index of 1.83 is described. The hepta-cycle precursor wherein dibenzo[g,p]chrysene and cyclopentanone are fused undertook double arylation to form a quaternary carbon. The resulting cardo scaffold was ranked with the primal cardo-monomer bis-phenol fluorene in chemical properties, which clarified the efficacy of dibenzo[g,p]chrysene.

権利情報:

• In Copyright
  

  This is the peer reviewed version of the following article: T. Yura, R. Noda, I. Okada, Z. Guo, T. Nakanishi, Y. Yamaoka, T. Iwasawa, Eur. J. Org. Chem. 2025, 28, e202401409, which has been published in final form at https://doi.org/10.1002/ejoc.202401409. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.

キーワード: Cardo structure, Dibenzo[g,p]chrysene, Refractive index, Bisphenol fluorene, Polycycles

刊行年月日: 2025-03-17

出版者: Wiley

掲載誌:

• European Journal of Organic Chemistry (ISSN: 1434193X) vol. 28 issue. 11

研究助成金:

• JSPS 22K05086
• NIMS NIMS Joint Research Hub Program

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5391

公開URL: https://doi.org/10.1002/ejoc.202401409

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更新時刻: 2025-03-31 17:00:22 +0900

MDRでの公開時刻: 2026-01-22 08:20:36 +0900