Composition- and structure-tunable CoNiFe hydroxide nanostructures toward enhanced oxygen evolution reaction

Zihan Zhang; Xingxin Jiang; Nattapol Ma; Jizhen Zhang; Emmanuel Picheau; Nobuyuki Sakai; Takayoshi Sasaki; Renzhi Ma

doi:10.1039/d6nr00271d

ジャーナル論文 Composition- and structure-tunable CoNiFe hydroxide nanostructures toward enhanced oxygen evolution reaction

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Zihan Zhang, Xingxin Jiang, Nattapol Ma, Jizhen Zhang, Emmanuel Picheau, Nobuyuki Sakai, Takayoshi Sasaki, Renzhi Ma. Composition- and structure-tunable CoNiFe hydroxide nanostructures toward enhanced oxygen evolution reaction. Nanoscale. 2026, 18 (25), 13397-13408. https://doi.org/10.1039/d6nr00271d

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(abstract)

Electrocatalytic performance of transition-metal layered double hydroxides (LDHs) can be substantially enhanced through compositional and structural engineering. Herein, ternary (CoNiFe) hydroxide nanocones featuring mixed tetrahedral (Td) and octahedral (Oh) coordination are rationally designed to boost oxygen evolution reaction (OER) activity. Binary CoNi hydroxide nanocones with mixed coordination are first synthesized, among which a Co:Ni ratio of 3:1 exhibits optimal performance with an overpotential of 339 mV at 10 mA cm−2. Subsequent Fe incorporation, followed by a topochemical oxidative intercalation process, convert the CoNiFe(II) hydroxides into CoNiFe(III) LDHs while retaining mixed Td/Oh coordination. Benefiting from the synergistic effects of multimetal composition and coordination modulation, the resulting
Co3Ni1Fe1 LDH nanocones achieve a markedly reduced overpotential of 280 mV. Furthermore, exfoliation into monolayer nanosheets leads to a further enhancement in catalytic activity by increasing exposure of accessible active sites, ultimately lowering the overpotential to 267 mV. This study highlights an effective strategy that integrates compositional optimization, coordination engineering, and structural modulation for the development of high-performance LDH electrocatalysts.

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