# Next-generation hydrogen peroxide sensors based on ordered carbonaceous frameworks derived from iron porphyrin

https://mdr.nims.go.jp/datasets/3b982a87-b059-4d57-9af5-f2204cfe3bb7

## File

- [Next-generation hydrogen peroxide sensors based on ordered carbonaceous frameworks derived from iron porphyrin.pdf](https://mdr.nims.go.jp/filesets/1c167043-7b05-422a-9da9-1f1e7c91d5a6/download) ([Detail](https://mdr.nims.go.jp/filesets/1c167043-7b05-422a-9da9-1f1e7c91d5a6.md))

## Id

3b982a87-b059-4d57-9af5-f2204cfe3bb7

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-06-04T05:47:34.491058Z

## Updated at

2025-07-16T07:14:54.207759Z

## Published at

2025-06-04T23:17:31.588543Z

## Doi

https://doi.org/10.48505/nims.5519

## First published url

https://doi.org/10.1080/14686996.2025.2506979

## Date published

2025-12-31

## Recorded date published

2025-12-31

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Next-generation hydrogen peroxide sensors based on ordered carbonaceous frameworks
    derived from iron porphyrin
  title_type: original
  lang: en

## Description

- description: Carbon materials with ordered frameworks and atomically dispersed metal
    sites, referred to as ordered carbonaceous frameworks (OCFs), have attracted considerable
    attention for their promising potential in fundamental research and diverse practical
    applications, particularly in electrocatalysis. In this work, we synthesize Fe-incorporated
    OCF (Fe-OCF) with a heme-like structure through structure-preserving pyrolysis
    of Fe-porphyrin with four ethynyl groups. Fe-OCF is characterized by its ordered
    microporous framework, incorporating atomically dispersed Fe(III) sites with a
    high content of 6.9 wt%, analogous to metal-organic frameworks. At the same time,
    Fe-OCF possesses the advantages of carbon materials, including chemical stability,
    thermal stability, and electrical conductivity. Remarkably, Fe-OCF mimics the
    functionality of a sensor enzyme by facilitating the redox reaction of hydrogen
    peroxide, which is regulated by an applied potential, thereby enabling bidirectional
    catalytic behavior. Fe-OCF exhibits a linear reduction current response to hydrogen
    peroxide, underscoring its efficient electron transfer and catalytic properties.
    Moreover, Fe-OCF demonstrates superior stability compared to molecular Fe-porphyrin,
    further emphasizing its potential application as a novel hydrogen peroxide sensor.
    These results emphasize the significant potential of Fe-based OCFs as advanced
    materials for artificial enzyme applications and next-generation hydrogen peroxide
    sensing technology.
  description_type: abstract
  lang: en

## Creator

- name: Akiko Yoshida
  role: author
  organization: a Techno Medica Co., Ltd.
- name: Koki Chida
  role: author
- name: Takeharu Yoshii
  role: author
- name: Shunsuke Shimizu
  role: author
- name: Hirotaka Nakatsuji
  role: author
- name: Kazuhide Kamiya
  role: author
- name: Yasuhisa Hasegawa
  role: author
- name: Tetsuji Itoh
  role: author
- name: Hirotomo Nishihara
  role: author

## Contact agent



## Publisher

organization: Taylor & Francis

## Managing organization



## Keyword

- subject: Ordered carbonaceous frameworks
  schema: not_defined
- subject: artificial heme enzymes
  schema: not_defined
- subject: hydrogen peroxide sensor
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by-nc/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Science and Technology of Advanced Materials
  issn: '14686996'
  volume: '26'
  issue: '1'
  article_number: '2506979'

## Conference



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## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



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## Fileset

- id: 1c167043-7b05-422a-9da9-1f1e7c91d5a6
  filename: Next-generation hydrogen peroxide sensors based on ordered carbonaceous
    frameworks derived from iron porphyrin.pdf
  content_type: application/pdf
  size: 2108591
  md5: a58d7d043b56add14b946e1f2e3559bb

## Thumbnail

fileset_id: 1c167043-7b05-422a-9da9-1f1e7c91d5a6
filename: Next-generation hydrogen peroxide sensors based on ordered carbonaceous
  frameworks derived from iron porphyrin.pdf