# Identification of Multiple Cs+ Adsorption Sites in a Hydroxy-interlayered Vermiculite-like Layered Silicate through 133Cs MAS NMR Analysis

https://mdr.nims.go.jp/datasets/35257e2d-4360-4879-8a39-ec9f278e2b0f

## File

- [Tansho Main revised 20161004_2.pdf](https://mdr.nims.go.jp/filesets/69e6bd15-b903-4b7b-8ab4-a8952c256fb8/download) ([Detail](https://mdr.nims.go.jp/filesets/69e6bd15-b903-4b7b-8ab4-a8952c256fb8.md))

## Id

35257e2d-4360-4879-8a39-ec9f278e2b0f

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-02-27T05:23:46.280612Z

## Updated at

2024-12-20T03:04:15.155133Z

## Published at

2024-12-20T03:31:00.227537Z

## Doi

https://doi.org/10.48505/nims.4427

## First published url

https://doi.org/10.1246/cl.160850

## Date published

2016-12-05

## Recorded date published

2016-12-5

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Identification of Multiple Cs+ Adsorption Sites in a Hydroxy-interlayered
    Vermiculite-like Layered Silicate through 133Cs MAS NMR Analysis
  title_type: original
  lang: en

## Description

- description: "133Cs magic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy
    revealed two Cs sites in Csadsorbed aluminium altered phlogopite (Cs Al-Phl),
    but only one site for Cs-adsorbed magnesium altered phlogopite (Cs Mg-Phl). Cesium
    ions in hydroxyl interlayered vermiculitelike\r\nlayered silicate reside at sites
    in both mica zones and in interlayer wedge zones of Al-Phl. It is likely that
    chemical exchange of Cs+ ions occurs between these two zones."
  description_type: abstract
  lang: en

## Creator

- name: Masataka Tansho
  role: author
  orcid: https://orcid.org/0000-0001-7986-3199
  organization: National Institute for Materials Science
- name: Kenji Tamura
  role: author
  orcid: https://orcid.org/0000-0001-6578-0923
  organization: National Institute for Materials Science
- name: Tadashi Shimizu
  role: author
  orcid: https://orcid.org/0000-0003-1202-8185
  organization: National Institute for Materials Science

## Contact agent



## Publisher

organization: The Chemical Society of Japan

## Managing organization



## Keyword

- subject: phlogopite
  schema: not_defined
- subject: mica
  schema: not_defined
- subject: interlayer wedge
  schema: not_defined
- subject: chemical exchange
  schema: not_defined

## Rights

- identifier: http://rightsstatements.org/vocab/InC/1.0/

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## Embargo



## Journal

- title: Chemistry Letters
  issn: '13480715'
  start_page: 1385
  end_page: 1387

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## Fileset

- id: 69e6bd15-b903-4b7b-8ab4-a8952c256fb8
  filename: Tansho Main revised 20161004_2.pdf
  content_type: application/pdf
  size: 256574
  md5: c424249173d8edcf9d1840298f6897f4

## Thumbnail

fileset_id: 69e6bd15-b903-4b7b-8ab4-a8952c256fb8
filename: Tansho Main revised 20161004_2.pdf