# Spin‐Selective Oxygen Evolution in Chiral Molecule‐Intercalated Layered Double Hydroxides

https://mdr.nims.go.jp/datasets/3521bffa-1b01-402c-8c35-e0c49460a4a5

## File

- [Advanced Science - 2026 - Huang - Spin‐Selective Oxygen Evolution in Chiral Molecule‐Intercalated Layered Double Hydroxides.pdf](https://mdr.nims.go.jp/filesets/7764872a-4235-4437-b8f0-43713ce0a100/download) ([Detail](https://mdr.nims.go.jp/filesets/7764872a-4235-4437-b8f0-43713ce0a100.md))

## Id

3521bffa-1b01-402c-8c35-e0c49460a4a5

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2026-09-24T03:15:45.896989Z

## Updated at

2026-09-24T05:15:10.107581Z

## Published at

2026-09-24T07:45:07.347379Z

## Doi



## First published url

https://doi.org/10.1002/advs.76090

## Date published

2026-06-16

## Recorded date published

2026-9

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Spin‐Selective Oxygen Evolution in Chiral Molecule‐Intercalated Layered Double
    Hydroxides
  title_type: original
  lang: en

## Description

- description: The chiral-induced spin selectivity (CISS) effect offers a novel paradigm
    for designing high-performance catalysts for spin-dependent oxygen evolution reactions
    (OER). Layered double hydroxides (LDHs), are widely used for oxygen evolution
    reaction (OER) due to their superior electrocatalytic activity and stability in
    alkaline environments. Here, we demonstrate that intercalating chiral phenylalanine
    molecules into CoFe-LDH induces spin-polarized OER via the CISS effect, while
    simultaneously expanding the interlayer spacing. The resulting chiral–inorganic
    hybrid interface directs the reaction along a lower-energy pathway, promoting
    the formation of triplet O¬2, and exhibits outstanding OER performance with a
    lower overpotential of 245 mV at 10 mA cm-2, as well as faster charge-transfer
    kinetics compared to its achiral counterpart. Using in situ XANES, in situ Raman
    spectroscopy, and nanoscale scanning electrochemical cell microscopy (SECCM),
    we further uncover the fundamental origin of this chiral-induced spin-selective
    behavior. This study establishes a general strategy for designing advanced, stable
    oxide-based electrocatalysts, where intercalated chiral molecules manipulate spin
    dynamics to improve reaction kinetics and selectivity.
  description_type: abstract
  lang: und

## Creator

- name: Chih‐Ying Huang
  role: author
  orcid: https://orcid.org/0009-0008-1658-1221
- name: Cheng‐Rong Wu
  role: author
- name: Yang‐Sheng Lu
  role: author
- name: Yu‐Ying Chang
  role: author
  orcid: https://orcid.org/0009-0003-5986-8779
- name: Chia‐Che Chang
  role: author
  orcid: https://orcid.org/0009-0009-9156-6010
- name: Tsung‐Hsin Liu
  role: author
  orcid: https://orcid.org/0009-0007-1059-7444
- name: Che‐Lun Lee
  role: author
- name: Jessie Shiue
  role: author
  orcid: https://orcid.org/0000-0001-6861-7953
- name: Yu‐Chang Lin
  role: author
- name: Wei‐Tsung Chuang
  role: author
- name: Huang‐Ming Tsai
  role: author
- name: Ya‐Lun Ho
  role: author
  orcid: https://orcid.org/0000-0001-8274-5978
- name: Jau‐Wern Chiou
  role: author
- name: Hua‐Shu Hsu
  role: author
  orcid: https://orcid.org/0000-0002-5773-2451
- name: Shao‐Sian Li
  role: author
  orcid: https://orcid.org/0000-0003-4236-1851
- name: Chia‐Chun Chen
  role: author
  orcid: https://orcid.org/0000-0001-6491-0482
- name: Way‐Faung Pong
  role: author
  orcid: https://orcid.org/0000-0002-1851-7564
- name: Chun‐Wei Chen
  role: author
  orcid: https://orcid.org/0000-0003-3096-249X

## Contact agent



## Publisher

organization: Wiley

## Managing organization



## Keyword

- subject: chiral-induced spin selectivity
  schema: not_defined
- subject: in situ observation
  schema: not_defined
- subject: layered double hydroxides
  schema: not_defined
- subject: molecule intercalation
  schema: not_defined
- subject: oxygen evolution reaction
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin



## Embargo



## Journal

- title: Advanced Science
  issn: '21983844'
  volume: '13'
  issue: '50'
  article_number: e76090

## Conference



## Related item



## Funding

- identifier: NSTC‐114‐2112‐M‐002‐032‐MY3
  funder_name: National Science and Technology Council
- identifier: 113‐2124‐M‐002‐007‐
  funder_name: National Science and Technology Council
- funder_name: National Synchrotron Radiation Research Center

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



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## Custom property



## Fileset

- id: 7764872a-4235-4437-b8f0-43713ce0a100
  filename: Advanced Science - 2026 - Huang - Spin‐Selective Oxygen Evolution in Chiral
    Molecule‐Intercalated Layered Double Hydroxides.pdf
  content_type: application/pdf
  size: 2954815
  md5: 65d3453aff356666d4bec82210549399

## Thumbnail

fileset_id: 7764872a-4235-4437-b8f0-43713ce0a100
filename: Advanced Science - 2026 - Huang - Spin‐Selective Oxygen Evolution in Chiral
  Molecule‐Intercalated Layered Double Hydroxides.pdf