# Stepwise Topochemical Linkage of Zirconium Oxo Clusters to Yield Black Zirconia Nanocrystals

https://mdr.nims.go.jp/datasets/3128f7ef-bb52-4378-9337-0df878e304a3

## File

- [black_zirconia_20251125.docx](https://mdr.nims.go.jp/filesets/f093008a-24f7-4e5d-b056-f050096b40aa/download) ([Detail](https://mdr.nims.go.jp/filesets/f093008a-24f7-4e5d-b056-f050096b40aa.md))

## Id

3128f7ef-bb52-4378-9337-0df878e304a3

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2026-01-21T00:21:24.338623Z

## Updated at

2026-01-21T00:46:20.503021Z

## Published at

2026-01-21T03:20:37.467334Z

## Doi

https://doi.org/10.48505/nims.6158

## First published url

https://doi.org/10.1021/acs.cgd.5c01036

## Date published

2025-12-17

## Recorded date published

2025-12-17

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Stepwise Topochemical Linkage of Zirconium Oxo Clusters to Yield Black Zirconia
    Nanocrystals
  title_type: original
  lang: en

## Description

- description: ジルコニウムオキソクラスターから酸化ジルコニウム結晶（蛍石構造）がトポケミカルな反応で、最小ユニットであるZr6クラスターを維持したまま、その縮合で結晶が形成されることを突き止めた論文。通常では見られない欠陥が大量に入り、電子スピンが観測されるのを始めて見出しました。
  description_type: abstract
  lang: und

## Creator

- name: Satoshi Tominaka
  role: author
  orcid: https://orcid.org/0000-0001-6474-8665
- name: Kazutaka Sonobe
  role: author
- name: Yoshitaka Matsushita
  role: author
  orcid: https://orcid.org/0000-0002-4968-8905
- name: Akihiko Machida
  role: author

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: black zirconia
  schema: not_defined
- subject: topochemical reaction
  schema: not_defined
- subject: pair distribution functions
  schema: not_defined
- subject: mechanism
  schema: not_defined
- subject: structural analysis
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin



## Embargo



## Journal

- title: Crystal Growth & Design
  issn: '15287483'
  volume: '25'
  issue: '24'
  start_page: 10364
  end_page: 10374

## Conference



## Related item



## Funding

- identifier: JPNP20003
  funder_name: New Energy and Industrial Technology Development Organization
- identifier: 22K14712
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: f093008a-24f7-4e5d-b056-f050096b40aa
  filename: black_zirconia_20251125.docx
  content_type: application/vnd.openxmlformats-officedocument.wordprocessingml.document
  size: 2055131
  md5: a2f61d491a7cef7781d8dbea6aa88269

## Thumbnail

fileset_id: f093008a-24f7-4e5d-b056-f050096b40aa
filename: black_zirconia_20251125.docx