# Fabrication of thin-film batteries composed of LiCoO2, Li3PO4, and Li layers

https://mdr.nims.go.jp/datasets/2bd00111-0dbd-4c78-899b-7c26bb69cc2f

## File

- [JSSE_TFB_review.pdf](https://mdr.nims.go.jp/filesets/102d7e54-04da-447e-839d-9aed75b27d97/download) ([Detail](https://mdr.nims.go.jp/filesets/102d7e54-04da-447e-839d-9aed75b27d97.md))

## Id

2bd00111-0dbd-4c78-899b-7c26bb69cc2f

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-04-17T03:54:32.631333Z

## Updated at

2024-04-17T07:30:21.661580Z

## Published at

2024-04-17T07:30:21.739180Z

## Doi



## First published url

https://doi.org/10.1007/s10008-024-05873-y

## Date published

2024-04-15

## Recorded date published

2024-12

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Fabrication of thin-film batteries composed of LiCoO2, Li3PO4, and Li layers
  title_type: original
  lang: en

## Description

- description: This paper reports the fabrication of thin film batteries which are
    composed of three stacking layers; LiCoO2, Li3PO4, and Li. First, a LiCoO2 layer
    is constructed on an electron-conductive substrate by pulsed laser deposition
    as a cathode. Crystallinity of LiCoO2 layer is mainly controlled by cationic ratio
    of Li and Co. Subsequently, an amorphous Li3PO4 layer with a high ionic conductivity
    is further deposited on the cathode LiCoO2 layer by radio frequency magnetron
    sputtering as a solid electrolyte. To avoid any possible damage which causes the
    formation of resistive species between LiCoO2 and Li3PO4, bias control of the
    substrate during Li3PO4 deposition is essential. Finally, a Li metal layer is
    deposited as an anode/current collector on the Li3PO4/LiCoO2 bilayer by resistive
    heating evaporation in vacuum at elevated temperature for the formation of low
    resistive interface. The fabricated three-layer thin film battery shows a high-rate
    capability when LiCoO2 layer is (104) oriented epitaxial film.
  description_type: abstract
  lang: und

## Creator

- name: Tsuyoshi Ohnishi
  role: author
  orcid: https://orcid.org/0000-0002-2333-7752
  organization: National Institute for Materials Science (NIMS)

## Contact agent



## Publisher

organization: Springer Science and Business Media LLC

## Managing organization



## Keyword

- subject: Li-ion battery
  schema: not_defined
- subject: all solid-state battery
  schema: not_defined
- subject: thin fiilm battery
  schema: not_defined
- subject: LiCoO2
  schema: not_defined
- subject: Li3PO4
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Journal of Solid State Electrochemistry
  issn: '14328488'

## Conference



## Related item



## Funding

- identifier: Materealize
  funder_name: Ministry of Education, Culture, Sports, Science and Technology, Japan
- identifier: JP19H05813
  funder_name: Japan Society for the Promotion of Science
- identifier: JPMJPF2016
  funder_name: Japan Science and Technology Agency

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



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## Custom property



## Fileset

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  filename: JSSE_TFB_review.pdf
  content_type: application/pdf
  size: 3052104
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## Thumbnail

fileset_id: 102d7e54-04da-447e-839d-9aed75b27d97
filename: JSSE_TFB_review.pdf