# Anionic Glycidyl Triazolyl Polymers: Oppositely Charged Analogs of Imidazolium-Based Cationic Glycidyl Triazolyl Polymers

https://mdr.nims.go.jp/datasets/2a3935bb-7151-4fba-b074-ce32861b7afe

## File

- [Manuscript_MDR.pdf](https://mdr.nims.go.jp/filesets/990ce0c4-d8a2-452e-94f4-4a73f2e56731/download) ([Detail](https://mdr.nims.go.jp/filesets/990ce0c4-d8a2-452e-94f4-4a73f2e56731.md))

## Id

2a3935bb-7151-4fba-b074-ce32861b7afe

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2023-12-05T23:49:47.261994Z

## Updated at

2024-11-10T07:30:12.723650Z

## Published at

2024-11-10T07:30:13.913351Z

## Doi

https://doi.org/10.48505/nims.4294

## First published url

https://doi.org/10.1021/acs.macromol.3c01501

## Date published

2023-11-28

## Recorded date published

2023-11-28

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: 'Anionic Glycidyl Triazolyl Polymers: Oppositely Charged Analogs of Imidazolium-Based
    Cationic Glycidyl Triazolyl Polymers'
  title_type: original
  lang: en

## Description

- description: Glycidyl triazolyl polymer (GTP)-based anionic poly(ionic liquid)s
    comprising the trifluoromethanesulfonimide (TFSI) anion pendant and the 1-ethyl-3-methylimidazolium
    (EMIM) countercation were synthesized through Cu(I)-catalyzed azide−alkyne cycloaddition
    between a glycidyl azide polymer and anionic alkyne derivatives. These polymers
    were designed as oppositely charged analogs of the cationic GTPs reported previously.
    The anionic GTPs were characterized by NMR, IR, size-exclusion chromatography,
    differential scanning calorimetry, thermogravimetric analysis, and impedance measurements.
    The anionic GTPs reported herein exhibited a lower critical solution temperature
    (LCST) type phase separation in acetone. The anionic GTPs with a longer side-chain
    spacer exhibited a lower glass transition temperature (Tg) and higher ionic conductivity
    (1.7 × 10−6 S cm−1 at 25 °C under anhydrous conditions).
  description_type: abstract
  lang: eng

## Creator

- name: Taichi Ikeda
  role: author
  orcid: https://orcid.org/0000-0001-6650-5798
  organization: National Institute for Materials Science
  department: Research Center for Macromolecules and Biomaterials

## Contact agent

- name: Taichi Ikeda
  email: IKEDA.Taichi@nims.go.jp
  orcid: https://orcid.org/0000-0001-6650-5798
  organization: National Institute for Materials Science
  department: Research Center for Macromolecules and Biomaterials
  ror: https://ror.org/

## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: Polyelectrolyte
  schema: not_defined
- subject: Ion conductive materials
  schema: not_defined
- subject: Glycidyl triazolyl polymer
  schema: not_defined
- subject: Functional polymer
  schema: not_defined
- subject: Poly(ionic liquid)
  schema: not_defined

## Rights

- description: This document is the Accepted Manuscript version of a Published Work
    that appeared in final form in Macromolecules, copyright © 2023 The Author after
    peer review and technical editing by the publisher. To access the final edited
    and published work see https://doi.org/10.1021/acs.macromol.3c01501.
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2023-11-10
end_date: 2024-11-10

## Journal

- title: MACROMOLECULES
  issn: '00249297'
  volume: '56'
  issue: '22'
  start_page: 9229
  end_page: 9236

## Conference



## Related item



## Funding

- identifier: 22K05246
  funder_name: JSPS

## Instrument



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## Specimen



## Chemical composition



## Structure for specimen



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## Fileset

- id: 990ce0c4-d8a2-452e-94f4-4a73f2e56731
  filename: Manuscript_MDR.pdf
  content_type: application/pdf
  size: 909834
  md5: bacbb2b765cad8214e7e62603b000478

## Thumbnail

fileset_id: 990ce0c4-d8a2-452e-94f4-4a73f2e56731
filename: Manuscript_MDR.pdf