# Lateral Heterometal Junction Rectifier Fabricated by Sequential Transmetallation of Coordination Nanosheet

https://mdr.nims.go.jp/datasets/20a76e7c-c268-4427-b58d-eab466dae9e5

## File

- [Angew Chem Int Ed - 2024 - Tan - Lateral Heterometal Junction Rectifier Fabricated by Sequential Transmetallation of.pdf](https://mdr.nims.go.jp/filesets/a5ba1141-b890-4782-9d13-c1ee249ffd11/download) ([Detail](https://mdr.nims.go.jp/filesets/a5ba1141-b890-4782-9d13-c1ee249ffd11.md))

## Id

20a76e7c-c268-4427-b58d-eab466dae9e5

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-02-28T10:09:06.209903Z

## Updated at

2024-03-01T07:37:51.228283Z

## Published at

2024-03-01T07:37:51.629357Z

## Doi



## First published url

https://doi.org/10.1002/anie.202318181

## Date published

2024-02-26

## Recorded date published

2024-2-26

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Lateral Heterometal Junction Rectifier Fabricated by Sequential Transmetallation
    of Coordination Nanosheet
  title_type: original
  lang: en

## Description

- description: Heterostructures of two-dimensional materials realise novel and enhanced
    physical phenomena, making them attractive research targets. Compared to inorganic
    materials, coordination nanosheets have virtually infinite combinations, leading
    to tunability of physical properties and are promising candidates for heterostructure
    fabrication. Although stacking of coordination materials into vertical heterostructures
    is widely reported, reports of lateral coordination material heterostructures
    are few. Here we show the successful fabrication of a seamless lateral heterojunction
    showing diode behaviour, by sequential and spatially limited immersion of a new
    metalladithiolene coordination nanosheet, Zn3BHT, into aqueous Cu(II) and Fe(II)
    solutions. Upon immersion, the Zn centres in insulating Zn3BHT are replaced by
    Cu or Fe ions, resulting in conductivity. The transmetallation is spatially confined,
    occurring only within the immersed area. We anticipate that our results will be
    a starting point towards exploring transmetallation of various two-dimensional
    materials to produce lateral heterojunctions, by providing a new and facile synthetic
    route.
  description_type: abstract
  lang: und

## Creator

- name: Choon Meng Tan
  role: author
- name: Naoya Fukui
  role: author
- name: Kenji Takada
  role: author
- name: Hiroaki Maeda
  role: author
- name: Ekaterina Selezneva
  role: author
  organization: National Institute for Materials Science
- name: Cédric Bourgès
  role: author
  orcid: https://orcid.org/0000-0001-9056-0420
  organization: National Institute for Materials Science
- name: Hiroyasu Masunaga
  role: author
- name: Sono Sasaki
  role: author
- name: Kazuhito Tsukagoshi
  role: author
  orcid: https://orcid.org/0000-0001-9710-2692
  organization: National Institute for Materials Science
- name: Takao Mori
  role: author
  orcid: https://orcid.org/0000-0003-2682-1846
  organization: National Institute for Materials Science
- name: Henning Sirringhaus
  role: author
- name: Hiroshi Nishihara
  role: author

## Contact agent



## Publisher

organization: Wiley

## Managing organization



## Keyword

- subject: Coordination Nanosheet
  schema: not_defined
- subject: Lateral Heterojunction
  schema: not_defined
- subject: Transmetallation
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Angewandte Chemie International Edition
  issn: '00448249'
  volume: '63'
  issue: '9'
  article_number: e202318181

## Conference



## Related item



## Funding

- identifier: JPMJCR15F2
  funder_name: Core Research for Evolutional Science and Technology
- identifier: JPJSCCA20190005
  funder_name: Japan Society for the Promotion of Science London
- identifier: EP/S030662/1
  funder_name: Engineering and Physical Sciences Research Council
- identifier: 19H05460
  funder_name: Japan Society for the Promotion of Science
- identifier: JPMJMI19A1
  funder_name: JST-Mirai Program
- identifier: 22K05055
  funder_name: Japan Society for the Promotion of Science
- identifier: 22K14569
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



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## Custom property



## Fileset

- id: a5ba1141-b890-4782-9d13-c1ee249ffd11
  filename: Angew Chem Int Ed - 2024 - Tan - Lateral Heterometal Junction Rectifier
    Fabricated by Sequential Transmetallation of.pdf
  content_type: application/pdf
  size: 1696075
  md5: 22d662fb818fbdb49efeaf5cf494540f

## Thumbnail

fileset_id: a5ba1141-b890-4782-9d13-c1ee249ffd11
filename: Angew Chem Int Ed - 2024 - Tan - Lateral Heterometal Junction Rectifier
  Fabricated by Sequential Transmetallation of.pdf