# Evolution of magnetization of Bi1-ySmyFe1-xTixO3 ceramics at the morphotropic phase boundary attested by multistep magnetization measurements, time aging and electric field

https://mdr.nims.go.jp/datasets/1e7ed271-c7a4-4757-bac1-28afe606754a

## File

- [Manuscript_2_rev-08-08-accepted-version.pdf](https://mdr.nims.go.jp/filesets/3c2e2b76-2586-4a86-b2ed-4163f92953c4/download) ([Detail](https://mdr.nims.go.jp/filesets/3c2e2b76-2586-4a86-b2ed-4163f92953c4.md))

## Id

1e7ed271-c7a4-4757-bac1-28afe606754a

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-10-28T00:36:24.717641Z

## Updated at

2024-10-28T01:05:08.050905Z

## Published at

2026-08-13T23:29:22.653701Z

## Doi

https://doi.org/10.48505/nims.4901

## First published url

https://doi.org/10.1016/j.ceramint.2024.08.237

## Date published

2024-08-14

## Recorded date published

2024-11

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Evolution of magnetization of Bi1-ySmyFe1-xTixO3 ceramics at the morphotropic
    phase boundary attested by multistep magnetization measurements, time aging and
    electric field
  title_type: original
  lang: en

## Description

- description: Bi1-ySmyFe1-xTixO3 ceramics with compositions at the rhombohedral-
    orthorhombic morphotropic phase boundary (y = 0.1, 0.12, 0 < x < 0.1) were prepared
    by solid state reaction method. Analysis of the crystal structure of the compounds
    based on the results of laboratory and synchrotron X-ray diffraction measurements
    as well as Raman spectroscopy experiments revealed a coexistence of the rhombohedral
    phase (SG R3c) and the anti-polar orthorhombic phase (SG Pbam) in the compounds
    Bi0.88Sm0.12Fe1-xTixO3 with 0 < x < 0.1; the compounds Bi0.9Sm0.10Fe1-xTixO3 are
    characterized by the mixed structural state for the concentration range 0 < x
    < 0.06 and by the single phase rhombohedral state within 0.06 < x < 0.1. Room
    temperature magnetization measurements demonstrate a gradual increase of remanent
    magnetization with Ti content in the compounds of both systems up to the maximal
    value of MR = 0.28 emu/g for compounds with x = 0.06 which is followed by a decrease
    in magnetization with further titanium doping. Temperature decrease leads to a
    reduction of remanent magnetization which is mainly caused by a partial recovery
    of spatially modulated spin structure occurred in the compounds of both systems.
    Time aging of the compounds for about 1 year leads to a drastic increase of MR,
    which is caused by a change in the structural phase ratio, homogeneity of the
    structural state and a contribution of unbounded spins demonstrated by low field
    measurements. Subjecting of the annealed compounds to external electric field
    of E = 40kV/cm leads to a decrease of magnetization associated with backward structural
    transformations and redistribution of the local structural defects in the compounds.
  description_type: abstract
  lang: und

## Creator

- name: D.V. Karpinsky
  role: author
- name: D.V. Zhaludkevich
  role: author
- name: S.I. Latushka
  role: author
- name: M.V. Silibin
  role: author
- name: N. Tran
  role: author
- name: A.А. Belik
  role: author
  orcid: https://orcid.org/0000-0001-9031-2355
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26
- name: F. Hussain
  role: author
- name: A.V. Trukhanov
  role: author
- name: Yuan Yao
  role: author
- name: B.D. Nhi
  role: author
- name: T.D. Thanh
  role: author
- name: P.T. Tho
  role: author

## Contact agent



## Publisher

organization: Elsevier BV

## Managing organization



## Keyword

- subject: BiFeO3
  schema: not_defined
- subject: SPring-8
  schema: not_defined
- subject: Synchrotron
  schema: not_defined

## Rights

- identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-08-14
end_date: 2026-08-14

## Journal

- title: Ceramics International
  issn: '02728842'
  volume: '50'
  issue: '22'
  start_page: 44806
  end_page: 44813

## Conference



## Related item



## Funding

- identifier: No.U2067216
  funder_name: National Natural Science Foundation of China
- identifier: No.U2067216
  funder_name: National Aerospace Science Foundation of China
- funder_name: Vancouver Island University
- identifier: 23-19-00347
  funder_name: Russian Science Foundation

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 3c2e2b76-2586-4a86-b2ed-4163f92953c4
  filename: Manuscript_2_rev-08-08-accepted-version.pdf
  content_type: application/pdf
  size: 4548138
  md5: 4aa389f520b3c17a6825e2dd1134afce

## Thumbnail

fileset_id: 3c2e2b76-2586-4a86-b2ed-4163f92953c4
filename: Manuscript_2_rev-08-08-accepted-version.pdf