Article Functional oligo- and polypeptide assemblies for photochemical, optical and electronic applications

Yohei Yamamoto (Department of Materials Science, Institute of Pure and Applied Sciences, University of Tsukuba,) ; Wey Yih Heah (Department of Materials Science, Institute of Pure and Applied Sciences, University of Tsukuba,) ; Kentaro Tashiro SAMURAI ORCID (Research Center for Macromolecules and Biomaterials/Biomaterials Field/Mechanobiology Group, National Institute for Materials ScienceROR)

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Citation
Yohei Yamamoto, Wey Yih Heah, Kentaro Tashiro. Functional oligo- and polypeptide assemblies for photochemical, optical and electronic applications. Materials Horizons. 2024, 11 (14), .
SAMURAI

Description:

(abstract)

we account self-assembled functional peptides, in which peptides with appropriately designed amino acid sequences can assemble functional groups on the side chains of the amino acids. First, we apply our design strategies for the synthesice of peptide-based materials with sequenced side chains with polar moieties, organic dyes and metal complexes. As a result, the synthetic oligopeptides exhibit inherent and photoinduced charge separation, electrochemical redox activities, as well as responses to bio-sequences. Next, catalytic and photocatalytic oxygen reduction reaction and hydrogen evolution reaction are shown by utilizing peptides with separated functionalities on both sides of the β-sheets by hybridizing with electro- and photoactive graphene oxide and metal nanoparticles. Finally, self-assembly of natural proteins that form micrometre-scale spherical geometry and fibres are utilized for optical and biomedical applications.

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Keyword: ペプチド

Date published: 2024-06-24

Publisher: Royal Society of Chemistry

Journal:

  • Materials Horizons (ISSN: 20516355) vol. 11 issue. 14

Funding:

Manuscript type: Publisher's version (Version of record)

MDR DOI:

First published URL: https://doi.org/10.1039/D4MH00218K

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Updated at: 2024-07-16 16:30:19 +0900

Published on MDR: 2024-07-16 16:30:19 +0900

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